Pure Appl. Chem., 2004, Vol. 76, No. 1, pp. 171-181
doi:10.1351/pac200476010171
Spectroscopy of interparticle interactions in ionic and molecular liquids: Novel approaches*
S. A. Kirillov
Institute for Technological and Information Innovations, P.O.Box 263, 03134 Kyiv, Ukraine, and Institute of Sorption and Problems of Endoecology, Ukrainian National Academy of Sciences, 13, Gen.Naumov St., 03680 Kyiv, Ukraine
Abstract:
The paper deals with several novel approaches to the studies of interactions and dynamics in liquids. A new, flexible time-correlation function is introduced. It has an analytical counterpart in the frequency domain and enables one to fit even badly overlapped vibrational line profiles obtaining dynamical information at the same time. As examples, quantitative description of the interaction potential in molten salts containing halide complexes of zinc and manganese is presented, the dynamic criterion of complex entities in a melt is introduced, and the spectroscopic features of molten alkali and alkaline earth halides are explained in terms of short-lived collision complexes. Finally, the model treatment of "anomalous" noncoincidence effects in liquids is discussed, and the contribution of repulsion and attraction forces resulting in frequency non-coincidences is separated.