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Pure Appl. Chem., 2004, Vol. 76, No. 3, pp. 477-494

doi:10.1351/pac200476030477

Synthetic applications of planar chiral cationic η3-allylmolybdenum complexes*

P. Kocienski, R. Bell, E. Bourque, J. A. Christopher, J. Cooksey, A. Gunn, A. Kuhl, Y. Li, S. Uppal, and J. Yuen

Department of Chemistry, Leeds University, Leeds LS2 9JT, UK; Department of Chemistry, Glasgow University, Glasgow G12 8QQ, UK; GlaxoSmithKline Research and Development, Medicines Research Centre, Stevenage, Hertfordshire SG1 2NY, UK


Abstract: The synthesis of planar chiral η3-allylmolybdenum complexes is described together with some examples of the nucleophilic addition of organocopper(I) reagents.