Pure and Applied Chemistry

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• Breugst Martin, Corral Bautista Francisco, Mayr Herbert: Nucleophilic Reactivities of the Anions of Nucleobases and Their Subunits. Chemistry A European Journal 2012, 18, 127. <http://dx.doi.org/10.1002/chem.201102411>
• Vistoli Giulio, Carini Marina, Aldini Giancarlo: Transforming dietary peptides in promising lead compounds: the case of bioavailable carnosine analogs. Amino Acid 2012. <http://dx.doi.org/10.1007/s00726-012-1224-z>
• Berionni Guillaume, Maji Biplab, Knochel Paul, Mayr Herbert: Nucleophilicity parameters for designing transition metal-free C–C bond forming reactions of organoboron compounds. Chem Sci 2012, 3, 878. <http://dx.doi.org/10.1039/c2sc00883a>
• Maji Biplab, Breugst Martin, Mayr Herbert: N-Heterocyclische Carbene: Organokatalysatoren mit mäßiger Nucleophilie, aber außerordentlich hoher Lewis-Basizität. angew chemie 2011, 123, 7047. <http://dx.doi.org/10.1002/ange.201102435>
• Lakhdar Sami, Ammer Johannes, Mayr Herbert: Laserblitzphotolytische Erzeugung α,β-ungesättigter Iminium-Ionen. angew chemie 2011, 123, 10127. <http://dx.doi.org/10.1002/ange.201103683>
• Mayr Herbert, Breugst Martin, Ofial Armin R.: Farewell to the HSAB Treatment of Ambident Reactivity. Angewandte Chemie-Int Ed 2011, 50, 6470. <http://dx.doi.org/10.1002/anie.201007100>
• Maji Biplab, Breugst Martin, Mayr Herbert: N-Heterocyclic Carbenes: Organocatalysts with Moderate Nucleophilicity but Extraordinarily High Lewis Basicity. Angewandte Chemie-Int Ed 2011, 50, 6915. <http://dx.doi.org/10.1002/anie.201102435>
• Lakhdar Sami, Ammer Johannes, Mayr Herbert: Generation of α,β-Unsaturated Iminium Ions by Laser Flash Photolysis. Angew Chem Int E 2011, 50, 9953. <http://dx.doi.org/10.1002/anie.201103683>
• De Rycke Nicolas, Couty François, David Olivier R. P.: Increasing the Reactivity of Nitrogen Catalysts. Chemistry A European Journal 2011, 17, 12852. <http://dx.doi.org/10.1002/chem.201101755>
• Streidl Nicolas, Mayr Herbert: Ionizing Power of Aprotic Solvents. Eur J Org Chem 2011, 2011, 2498. <http://dx.doi.org/10.1002/ejoc.201001700>
• Berionni Guillaume, Branca Mathieu, Pégot Bruce, Marrot Jérome, Kizilian Elyane, Goumont Régis: The N-Alkylation of Substituted 4-Tetrazolo[1,5-a]pyridines: Easy Access to a New Series of Electrophiles. Eur J Org Chem 2011, 2011, 5104. <http://dx.doi.org/10.1002/ejoc.201100595>
• Zimniak Piotr: Relationship of electrophilic stress to aging. Radic Biol Med 2011, 51, 1087. <http://dx.doi.org/10.1016/j.freeradbiomed.2011.05.039>
• Appel Roland, Mayr Herbert: Quantification of the Electrophilic Reactivities of Aldehydes, Imines, and Enones. J Am Chem Soc 2011, 133, 8240. <http://dx.doi.org/10.1021/ja200820m>
• Larouche-Gauthier Robin, Elford Tim G., Aggarwal Varinder K.: Ate Complexes of Secondary Boronic Esters as Chiral Organometallic-Type Nucleophiles for Asymmetric Synthesis. S J Am Chem Soc 2011, 133, 16794. <http://dx.doi.org/10.1021/ja2077813>
• Maji Biplab, Joannesse Caroline, Nigst Tobias A., Smith Andrew D., Mayr Herbert: Nucleophilicities and Lewis Basicities of Isothiourea Derivatives. J Org Chem 2011, 76, 5104. <http://dx.doi.org/10.1021/jo200803x>
• Pereira Florbela, Latino Diogo A. R. S., Aires-de-Sousa Joao: Estimation of Mayr Electrophilicity with a Quantitative Structure–Property Relationship Approach Using Empirical and DFT Descriptors. J Org Chern 2011, 76, 9312. <http://dx.doi.org/10.1021/jo201562f>
• Zenz Ivo, Mayr Herbert: Electrophilicities of trans-β-Nitrostyrenes. J Org Chern 2011, 76, 9370. <http://dx.doi.org/10.1021/jo201678u>
• Lakhdar Sami, Mayr Herbert: Counterion effects in iminium-activated electrophilic aromatic substitutions of pyrroles. Chem Commun 2011, 47, 1866. <http://dx.doi.org/10.1039/c0cc04295a>
• Duan Xin-Hua, Maji Biplab, Mayr Herbert: Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions. Biomol Chem 2011, 9, 8046. <http://dx.doi.org/10.1039/c1ob06245j>
• Benfatti Fides, Benedetto Elena, Cozzi Pier Giorgio: Organocatalytic Stereoselective α-Alkylation of Aldehydes with Stable Carbocations. Chem Asian J 2010, 5, 2047. <http://dx.doi.org/10.1002/asia.201000160>
• Wang Chen, Fu Yao, Guo Qing-Xiang, Liu Lei: First-Principles Prediction of Nucleophilicity Parameters for π Nucleophiles: Implications for Mechanistic Origin of Mayr’s Equation. Chem Eur J 2010, 16, 2586. <http://dx.doi.org/10.1002/chem.200902484>
• Baidya Mahiuddin, Remennikov Grygoriy Y., Mayer Peter, Mayr Herbert: S_N2’ versus S_N2 Reactivity: Control of Regioselectivity in Conversions of Baylis-Hillman Adducts. Chem Eur J 2010, 16, 1365. <http://dx.doi.org/10.1002/chem.200902487>
• Horn Markus, Mayr Herbert: Electrophilicity versus Electrofugality of Tritylium Ions in Aqueous Acetonitrile. Chem Eur J 2010, 16, 7478. <http://dx.doi.org/10.1002/chem.200902670>
• Lakhdar Sami, Terrier François, Vichard Dominique, Berionni Guillaume, El Guesmi Nizar, Goumont Régis, Boubaker Taoufik: The Diels-Alder Reaction of 4,6-Dinitrobenzofuroxan with 1-Trimethylsilyloxybuta-1,3-diene: A Case Example of a Stepwise Cycloaddition. Chem Eur J 2010, NA. <http://dx.doi.org/10.1002/chem.200903008>
• Kanzian Tanja, Nicolini Simona, De Crescentini Lucia, Attanasi Orazio A., Ofial Armin R., Mayr Herbert: Electrophilic Reactivities of 1,2-Diaza-1,3-dienes. Chem Eur J 2010, 16, 12008. <http://dx.doi.org/10.1002/chem.201000828>
• Appel Roland, Mayr Herbert: Nucleophilic Reactivities of Sulfur Ylides and Related Carbanions: Comparison with Structurally Related Organophosphorus Compounds. Chem Eur J 2010, 16, 8610. <http://dx.doi.org/10.1002/chem.201001455>
• Kanzian Tanja, Mayr Herbert: Electrophilic Reactivities of Azodicarboxylates. Chem Eur J 2010, 16, 11670. <http://dx.doi.org/10.1002/chem.201001598>
• Mayr Herbert, Nolte Christoph: Kinetics of the Solvolyses of Fluoro-Substituted Benzhydryl Derivatives: Reference Electrofuges for the Development of a Comprehensive Nucleofugality Scale. Eur J Org Chem 2010, 2010, 01435. <http://dx.doi.org/10.1002/ejoc.200901400>
• Langhals Heinz, Pust Tim: Axially Extended Perylene Dyes. Eur J Org Chem 2010, 2010, 3140. <http://dx.doi.org/10.1002/ejoc.201000230>
• Streidl Nicolas, Branzan Ramona, Mayr Herbert: Nucleophilicities and Nucleofugalities of Organic Carbonates. Eur J Org Chem 2010, 2010, 4205. <http://dx.doi.org/10.1002/ejoc.201000414>
• Mayr Herbert, Ofial Armin R.: Und es geht doch: Nucleophilieskalen für die Syntheseplanung. Nachr Chem 2010, 56, 871. <http://dx.doi.org/10.1002/nadc.200858379>
• Ammer Johannes, Baidya Mahiuddin, Kobayashi Shinjiro, Mayr Herbert: Nucleophilic reactivities of tertiary alkylamines. J Phys Org Chem 2010, 23, 1029. <http://dx.doi.org/10.1002/poc.1707>
• Lakhdar Sami, Ofial Armin R., Mayr Herbert: Reactivity parameters for rationalizing iminium-catalyzed reactions. J Phys Org Chem 2010, 23, 886. <http://dx.doi.org/10.1002/poc.1737>
• Appel Roland, Hartmann Nicolai, Mayr Herbert: Scope and Limitations of Cyclopropanations with Sulfur Ylides. J Am Chem Soc 2010, 132, 17894. <http://dx.doi.org/10.1021/ja1084749>
• Baidya Mahiuddin, Kobayashi Shinjiro, Mayr Herbert: Nucleophilicity and Nucleofugality of Phenylsulfinate (PhSO₂⁻): A Key to Understanding its Ambident Reactivity. J Am Chem Soc 2010, 132, 4796. <http://dx.doi.org/10.1021/ja9102056>
• Buncel Erwin, Terrier François: Assessing the superelectrophilic dimension through σ-complexation, SNAr and Diels–Alder reactivity. Org Biomol Chem 2010, 8, 2285. <http://dx.doi.org/10.1039/b923983a>
• Baidya Mahiuddin, Brotzel Frank, Mayr Herbert: Nucleophilicities and Lewis basicities of imidazoles, benzimidazoles, and benzotriazoles. Org Biomol Chem 2010, 8, 1929. <http://dx.doi.org/10.1039/c000965b>
• Richter Dorothea, Mayr Herbert: Hydrid-Donor-Stärke von 1,4-Dihydropyridinen: ein Vergleich mit π-Nucleophilen und Borhydrid-Anionen. Angew Chem 2009, 121, 1992. <http://dx.doi.org/10.1002/ange.200804263>
• Lakhdar Sami, Appel Roland, Mayr Herbert: Wie werden Iminium-katalysierte Cyclopropanierungen durch elektrostatische Aktivierung gesteuert?. Angew Chem 2009, 121, 5134. <http://dx.doi.org/10.1002/ange.200900933>
• Richter Dorothea, Mayr Herbert: Hydride-Donor Abilities of 1,4-Dihydropyridines: A Comparison with π Nucleophiles and Borohydride Anions. Angew Chem Int Ed 2009, 48, 1958. <http://dx.doi.org/10.1002/anie.200804263>
• Lakhdar Sami, Appel Roland, Mayr Herbert: How Does Electrostatic Activation Control Iminium-Catalyzed Cyclopropanations?. Angew Chem Int Ed 2009, 48, 5034. <http://dx.doi.org/10.1002/anie.200900933>
• Shi Lei, Horn Markus, Kobayashi Shinjiro, Mayr Herbert: Carbocationic n-endo-trig Cyclizations. Chem Eur J 2009, 15, 8533. <http://dx.doi.org/10.1002/chem.200901246>
• Kędziorek Mariusz, Mayer Peter, Mayr Herbert: Nucleophilic Reactivities of Azulene and Fulvenes. Eur J Org Chem 2009, 2009, 1202. <http://dx.doi.org/10.1002/ejoc.200801099>
• Richter Dorothea, Hampel Nathalie, Singer Thomas, Ofial Armin R., Mayr Herbert: Synthesis and Characterization of Novel Quinone Methides: Reference Electrophiles for the Construction of Nucleophilicity Scales. Eur J Org Chem 2009, 2009, 3203. <http://dx.doi.org/10.1002/ejoc.200900299>
• Kanzian Tanja, Nigst Tobias A., Maier Andreas, Pichl Stefan, Mayr Herbert: Nucleophilic Reactivities of Primary and Secondary Amines in Acetonitrile. Eur J Org Chem 2009, 2009, 6379. <http://dx.doi.org/10.1002/ejoc.200900925>
• Appel Roland, Loos Robert, Mayr Herbert: Nucleophilicity Parameters for Phosphoryl-Stabilized Carbanions and Phosphorus Ylides: Implications for Wittig and Related Olefination Reactions. J Am Chem Soc 2009, 131, 704. <http://dx.doi.org/10.1021/ja8056216>
• Phan Thanh Binh, Nolte Christoph, Kobayashi Shinjiro, Ofial Armin R., Mayr Herbert: Can One Predict Changes from S_N1 to S_N2 Mechanisms?. J Am Chem Soc 2009, 131, 11392. <http://dx.doi.org/10.1021/ja903207b>
• Cozzi Pier Giorgio, Zoli Luca: A Rational Approach towards the Nucleophilic Substitutions of Alcohols “on Water”. Angew Chem 2008, 120, 4230. <http://dx.doi.org/10.1002/ange.200800622>
• Lakhdar Sami, Tokuyasu Takahiro, Mayr Herbert: Elektrophile Reaktivität α,β-ungesättigter Iminiumionen. Angew Chem 2008, 120, 8851. <http://dx.doi.org/10.1002/ange.200802889>
• Cozzi Pier Giorgio, Zoli Luca: A Rational Approach towards the Nucleophilic Substitutions of Alcohols “on Water”. Angew Chem Int Ed 2008, 47, 4162. <http://dx.doi.org/10.1002/anie.200800622>
• Lakhdar Sami, Tokuyasu Takahiro, Mayr Herbert: Electrophilic Reactivities of α,β-Unsaturated Iminium Ions. Angew Chem Int Ed 2008, 47, 8723. <http://dx.doi.org/10.1002/anie.200802889>
• Seeliger Florian, Błażej Sylwia, Bernhardt Sebastian, Mąkosza Mieczysław, Mayr Herbert: Reactions of Nitroheteroarenes with Carbanions: Bridging Aromatic, Heteroaromatic, and Vinylic Electrophilicity. Chem Eur J 2008, 14, 6108. <http://dx.doi.org/10.1002/chem.200800329>
• Błażej Sylwia, Mąkosza Mieczysław: Substituent Effects on the Electrophilic Activity of Nitroarenes in Reactions with Carbanions. Chem Eur J 2008, 14, 11113. <http://dx.doi.org/10.1002/chem.200800821>
• Kaumanns Oliver, Lucius Roland, Mayr Herbert: Determination of the Electrophilicity Parameters of Diethyl Benzylidenemalonates in Dimethyl Sulfoxide: Reference Electrophiles for Characterizing Strong Nucleophiles. Chem Eur J 2008, 14, 9675. <http://dx.doi.org/10.1002/chem.200801277>
• Nigst Tobias A., Westermaier Martin, Ofial Armin R., Mayr Herbert: Nucleophilic Reactivities of Pyrroles. Eur J Org Chem 2008, 2008, 2369. <http://dx.doi.org/10.1002/ejoc.200800092>
• Forlani Luciano, Attanasi Orazio A., Boga Carla, De Crescentini Lucia, Del Vecchio Erminia, Favi Gianfranco, Mantellini Fabio, Tozzi Silvia, Zanna Nicola: Unusual Reactions Between Aromatic Carbon Supernucleophiles and 1,2-Diazabuta-1,3-dienes: Useful Routes to New Pyrazolone and Cinnoline Derivatives. Eur J Org Chem 2008, 2008, 4357. <http://dx.doi.org/10.1002/ejoc.200800445>
• Ohta Akihiro, Dahl Klaus, Raab Rainer, Geittner Jochen, Huisgen Rolf: Diazodiphenylmethane and Monosubstituted Butadienes: Kinetics and a New Chapter of Vinylcyclopropane Chemistry. HCA 2008, 91, 783. <http://dx.doi.org/10.1002/hlca.200890081>
• Mayr Herbert, Ofial Armin R.: Do general nucleophilicity scales exist?. J Phys Org Chem 2008, 21, 584. <http://dx.doi.org/10.1002/poc.1325>
• Baidya M., Mayr Herbert: Nucleophilicities and carbon basicities of DBU and DBN. Chem Commun 2008, 1792. <http://dx.doi.org/10.1039/b801811a>
• Seeliger Florian, Mayr Herbert: Nucleophilic reactivities of benzenesulfonyl-substituted carbanions. Org Biomol Chem 2008, 6, 3052. <http://dx.doi.org/10.1039/b805604h>
• Tumanov Vasily V., Tishkov Alexander A., Mayr Herbert: Nucleophilie-Parameter von Alkyl- und Arylisocyaniden. Angew Chem 2007, 119, 3633. <http://dx.doi.org/10.1002/ange.200605205>
• Baidya Mahiuddin, Kobayashi Shinjiro, Brotzel Frank, Schmidhammer Uli, Riedle Eberhard, Mayr Herbert: DABCO oder DMAP – worauf beruht ihr Unterschied in der Organokatalyse?. Angew Chem 2007, 119, 6288. <http://dx.doi.org/10.1002/ange.200701489>
• Tumanov Vasily V., Tishkov Alexander A., Mayr Herbert: Nucleophilicity Parameters for Alkyl and Aryl Isocyanides. Angew Chem Int Ed 2007, 46, 3563. <http://dx.doi.org/10.1002/anie.200605205>
• Baidya Mahiuddin, Kobayashi Shinjiro, Brotzel Frank, Schmidhammer Uli, Riedle Eberhard, Mayr Herbert: DABCO and DMAP—Why Are They Different in Organocatalysis?. Angew Chem Int Ed 2007, 46, 6176. <http://dx.doi.org/10.1002/anie.200701489>
• Lakhdar Sami, Goumont Régis, Berionni Guillaume, Boubaker Taoufik, Kurbatov Sergey, Terrier François: Superelectrophilicity of the Nitroolefinic Fragment of 4-Nitrobenzodifuroxan in Michael-Type Reactions with Indoles: A Kinetic Study in Acetonitrile. Chem Eur J 2007, 13, 8317. <http://dx.doi.org/10.1002/chem.200700676>
• Berger Stefan T. A., Seeliger Florian H., Hofbauer Florian, Mayr Herbert: Electrophilicity parameters for 2-benzylidene-indan-1,3-diones—a systematic extension of the benzhydrylium based electrophilicity scale. Org Biomol Chem 2007, 5, 3020. <http://dx.doi.org/10.1039/b708025e>
• Brotzel Frank, Mayr Herbert: Nucleophilicities of amino acids and peptides. Org Biomol Chem 2007, 5, 3814. <http://dx.doi.org/10.1039/b713778h>
• Mayr Herbert, Ofial Armin R.: Das Reaktivitäts-Selektivitäts-Prinzip: ein unzerstörbarer Mythos der organischen Chemie. Angew Chem 2006, 118, 1876. <http://dx.doi.org/10.1002/ange.200503273>
• Phan Thanh Binh, Breugst Martin, Mayr Herbert: Auf dem Weg zu einer allgemeinen Nucleophilie-Skala?. Angew Chem 2006, 118, 3954. <http://dx.doi.org/10.1002/ange.200600542>
• Mayr Herbert, Ofial Armin R.: The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry. Angew Chem Int Ed 2006, 45, 1844. <http://dx.doi.org/10.1002/anie.200503273>
• Phan Thanh Binh, Breugst Martin, Mayr Herbert: Towards a General Scale of Nucleophilicity?. Angew Chem Int Ed 2006, 45, 3869. <http://dx.doi.org/10.1002/anie.200600542>
• Denegri Bernard, Streiter André, Jurić Sandra, Ofial Armin R., Kronja Olga, Mayr Herbert: Kinetics of the Solvolyses of Benzhydryl Derivatives: Basis for the Construction of a Comprehensive Nucleofugality Scale. Chem Eur J 2006, 12, 1648. <http://dx.doi.org/10.1002/chem.200500845>
• Denegri Bernard, Ofial Armin R., Jurić Sandra, Streiter André, Kronja Olga, Mayr Herbert: How Fast Do RX Bonds Ionize? A Semiquantitative Approach. Chem Eur J 2006, 12, 1657. <http://dx.doi.org/10.1002/chem.200500847>
• Bentley T. William: Additivity Rules Using Similarity Models for Chemical Reactivity: Calculation and Interpretation of Electrofugality and Nucleofugality. Chem Eur J 2006, 12, 6514. <http://dx.doi.org/10.1002/chem.200600517>
• Binh Phan Thanh, Mayr Herbert: Nucleophilicity Parameters for Carbanions in Methanol. Eur J Org Chem 2006, 2006, 2530. <http://dx.doi.org/10.1002/ejoc.200500769>
• Dyker Gerald, Hagel Marcel, Muth Oliver, Schirrmacher Christian: Sterically Stabilizedp-Quinodimethanes by Nucleophilic Aromatic Substitution. Eur J Org Chem 2006, 2006, 2134. <http://dx.doi.org/10.1002/ejoc.200600002>