Pure Appl. Chem., 2005, Vol. 77, No. 12, pp. 2021-2027
doi:10.1351/pac200577122021
Transition-metal-catalyzed reactions of carbon-heteroatom bond formation by substitution and addition processes*
I. P. Beletskaya
Chemistry Department, Moscow State University, Leninskie Gory, 119992, Moscow, Russia
Abstract:
Two types of transition-metal-catalyzed cross-coupling reactions, which both lead to the formation of carbon-heteroatom bonds, are considered: RX + E-H and E-X + RM. The potential of addition reactions of E-H or E-E to double or triple bond in C-E bond formation is also demonstrated.
Keywords: bond formation; carbon-carbon; carbon-heteroatom; homogeneous catalysts; Transition-metal-catalyzed reactions; Ullmann reaction.