Pure Appl. Chem., 2005, Vol. 77, No. 12, pp. 2073-2081
doi:10.1351/pac200577122073
Oxacycle synthesis via radical cyclization of β-alkoxyacrylates*
Eun Lee
Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea
Abstract:
Oxolane and oxane units in oxacyclic natural products were prepared via radical cyclization reaction of β-alkoxyacrylates, β-alkoxymethacrylates, and β-alkoxyvinyl ketones.
Keywords: ambruticin; lasonolide A; pamamycin-607; radical cyclization; SCH 351448; β-Alkoxyacrylates.
*Paper based on a presentation at the 7th IUPAC International Conference on Heteroatom Chemistry (ICHAC-7), Shanghai, China, 21-25 August 2004. Other presentations are published in this issue, pp. 1985-2132.