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Pure Appl. Chem., 2005, Vol. 77, No. 5, pp. 815-826

http://dx.doi.org/10.1351/pac200577050815

POLYMER DIVISION

Polyaniline: Thin films and colloidal dispersions (IUPAC Technical Report)

Jaroslav Stejskal1* and Irina Sapurina2

1 Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06; Prague 6, Czech Republic
2 Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg 199004, Russia

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  • Yun Jumi, Kim Hyung-Il: Electromagnetic interference shielding effects of polyaniline-coated multi-wall carbon nanotubes/maghemite nanocomposites. Pol Bull 2012, 68, 561. <http://dx.doi.org/10.1007/s00289-011-0651-4>
  • Coşkun Elçin, Martínez-Ramírez Shaida Marisol, Antunez-Flores Wilber, Hernández-Escobar Claudia Alejandra, Zaragoza-Contreras Erasto Armando: Improving polyaniline processability by grafting acrylic copolymer. Synthetic Metal 2012, 162, 344. <http://dx.doi.org/10.1016/j.synthmet.2011.12.016>
  • Inzelt György: Rise and rise of conducting polymers. J Solid State Electrochem 2011, 15, 1711. <http://dx.doi.org/10.1007/s10008-011-1338-3>
  • Martínez Maria L., Luna D’Amicis Froilán A., Beltramone Andrea R., Gómez Costa Marcos B., Anunziata Oscar A.: Synthesis and characterization of new composites: PANI/Na-AlSBA-3 and PANI/Na-AlSBA-16. Mat Res Bul 2011, 46, 1011. <http://dx.doi.org/10.1016/j.materresbull.2011.03.018>
  • Bober Patrycja, Stejskal Jaroslav, Trchová Miroslava, Prokeš Jan: Polyaniline–silver composites prepared by the oxidation of aniline with mixed oxidants, silver nitrate and ammonium peroxydisulfate: The control of silver content. Poly 2011, 52, 5947. <http://dx.doi.org/10.1016/j.polymer.2011.10.025>
  • Lobotka P., Kunzo P., Kovacova E., Vavra I., Krizanova Z., Smatko V., Stejskal J., Konyushenko E.N., Omastova M., Spitalsky Z.: Thin polyaniline and polyaniline/carbon nanocomposite films for gas sensing. This Solid Films 2011, 519, 4123. <http://dx.doi.org/10.1016/j.tsf.2011.01.177>
  • Rozlívková Zuzana, Trchová Miroslava, Šeděnková Ivana, Špírková Milena, Stejskal Jaroslav: Structure and stability of thin polyaniline films deposited in situ on silicon and gold during precipitation and dispersion polymerization of aniline hydrochloride. This Solid Films 2011, 519, 5933. <http://dx.doi.org/10.1016/j.tsf.2011.03.025>
  • Zujovic Zoran D., Metson James B.: Nanostructured Aniline Oxidation Products: Self-Assembled Films at the Air/Liquid Interface. Langmiur 2011, 27, 7776. <http://dx.doi.org/10.1021/la102684d>
  • Tran Henry D., D'Arcy Julio M., Wang Yue, Beltramo Peter J., Strong Veronica A., Kaner Richard B.: The oxidation of aniline to produce “polyaniline”: a process yielding many different nanoscale structures. J Mater Chem 2011, 21, 3534. <http://dx.doi.org/10.1039/c0jm02699a>
  • Prokeš Jan, Varga Martin, Křivka Ivo, Rudajevová Alexandra, Stejskal Jaroslav: The influence of compression pressure on transport properties of polyaniline. J Mater Chem 2011, 21, 5038. <http://dx.doi.org/10.1039/c0jm03087b>
  • Zhao Ya-Ping, Cai Zai-Sheng, Fu Xiao-Lan: Effect of polymeric additives on the formation and properties of polyaniline films on polyester fabrics. joti 2011, 1. <http://dx.doi.org/10.1080/00405000.2011.603203>
  • Molina M A, Rivarola C R, Miras M C, Lescano D, Barbero C A: Nanocomposite synthesis by absorption of nanoparticles into macroporous hydrogels. Building a chemomechanical actuator driven by electromagnetic radiation. J of Inst Physics Nanotechnology 2011, 22, 245504. <http://dx.doi.org/10.1088/0957-4484/22/24/245504>
  • Trchová Miroslava, Stejskal Jaroslav: Polyaniline: The infrared spectroscopy of conducting polymer nanotubes (IUPAC Technical Report). Pure and App Chemis 2011, 1. <http://dx.doi.org/10.1351/PAC-REP-10-02-01>
  • Omastová Mária, Mičušík Matej: Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation. Chem Pap 2011. <http://dx.doi.org/10.2478/s11696-011-0120-4>
  • Stejskal Jaroslav, Trchová Miroslava, Hromádková Jir̆ina, Kovár̆ová Jana, Kalendová Andrea: The carbonization of colloidal polyaniline nanoparticles to nitrogen-containing carbon analogues. Polym Int 2010, 59, 875. <http://dx.doi.org/10.1002/pi.2858>
  • Bober Patrycja, Stejskal Jaroslav, Trchová Miroslava, Hromádková Jiřina, Prokeš Jan: Polyaniline-coated silver nanowires. React & Funct Polym 2010, 70, 656. <http://dx.doi.org/10.1016/j.reactfunctpolym.2010.05.009>
  • Majumdar D., Saha S. K.: Observation of ferroelectric response in conjugated polymer nanotubes. Appl Phys Lett 2010, 96, 183113. <http://dx.doi.org/10.1063/1.3425894>
  • Sonavane A C, Inamdar A I, Deshmukh H P, Patil P S: Multicoloured electrochromic thin films of NiO/PANI. J Phys D Appl Phys 2010, 43, 315102. <http://dx.doi.org/10.1088/0022-3727/43/31/315102>
  • Stejskal Jaroslav, Bogomolova Olga E, Blinova Natalia V, Trchová Miroslava, Šeděnková Ivana, Prokeš Jan, Sapurina Irina: Mixed electron and proton conductivity of polyaniline films in aqueous solutions of acids: beyond the 1000 S cm−1 limit. Polym Int 2009, 58, 872. <http://dx.doi.org/10.1002/pi.2605>
  • Wang C.-H., Chen C.-C., Hsu H.-C., Du H.-Y., Chen C.-P., Hwang J.-Y., Chen L.C., Shih H.-C., Stejskal J., Chen K.H.: Low methanol-permeable polyaniline/Nafion composite membrane for direct methanol fuel cells. J Power Sources - 2009, 190, 279. <http://dx.doi.org/10.1016/j.jpowsour.2008.12.125>
  • Ayad M.M., Amer W.A., Stejskal J.: Effect of iodine solutions on polyaniline films. This Solid Films 2009, 517, 5969. <http://dx.doi.org/10.1016/j.tsf.2009.03.129>
  • Lee Seung-Yong, Choi Gyoung-Rin, Lim Hyuneui, Lee Kyung-Mi, Lee Sang-Kwon: Electronic transport characteristics of electrolyte-gated conducting polyaniline nanowire field-effect transistors. Appl Phys Lett 2009, 95, 013113. <http://dx.doi.org/10.1063/1.3176444>
  • Sapurina Irina, Stejskal Jaroslav: The mechanism of the oxidative polymerization of aniline and the formation of supramolecular polyaniline structures. Polym Int 2008, 57, 1295. <http://dx.doi.org/10.1002/pi.2476>
  • Šeděnková Ivana, Prokeš Jan, Trchová Miroslava, Stejskal Jaroslav: Conformational transition in polyaniline films – Spectroscopic and conductivity studies of ageing. Polym Deg Stabil 2008, 93, 428. <http://dx.doi.org/10.1016/j.polymdegradstab.2007.11.015>
  • Šeděnková Ivana, Trchová Miroslava, Stejskal Jaroslav: Thermal degradation of polyaniline films prepared in solutions of strong and weak acids and in water – FTIR and Raman spectroscopic studies. Polym Deg Stabil 2008, 93, 2147. <http://dx.doi.org/10.1016/j.polymdegradstab.2008.08.007>
  • Stejskal Jaroslav, Trchová Miroslava, Blinova Natalia V., Konyushenko Elena N., Reynaud Stéphanie, Prokeš Jan: The reaction of polyaniline with iodine. Poly 2008, 49, 180. <http://dx.doi.org/10.1016/j.polymer.2007.11.023>
  • Trchová Miroslava, Blinova Natalia V., Holler Petr, Konyushenko Elena N., Stejskal Jaroslav: Polymerization of aniline in ice. Synthetic Metal 2008, 158, 927. <http://dx.doi.org/10.1016/j.synthmet.2008.06.015>
  • Kuzmin S.V., Sáha P., Sudar N.T., Zakrevskii V.A., Sapurina I., Solosin S., Trchová M., Stejskal J.: Electrical strength of thin polyaniline films. This Solid Films 2008, 516, 2181. <http://dx.doi.org/10.1016/j.tsf.2007.07.138>
  • Stejskal Jaroslav, Trchová Miroslava, Kovářová Jana, Prokeš Jan, Omastová Mária: Polyaniline-coated cellulose fibers decorated with silver nanoparticles. Chem Pap 2008, 62, 181. <http://dx.doi.org/10.2478/s11696-008-0009-z>
  • . Theofilus A. Tockary, . W. Endang Asijati, . Yanti S. Soebianto: Model of in situ Polyaniline Film Coating on Mylar: Influence of Aniline Polymerization Parameters . J Applied Sci 2008, 8, 2041. <http://dx.doi.org/10.3923/jas.2008.2041.2049>
  • Stejskal Jaroslav, Trchová Miroslava, Brodinová Jitka, Sapurina Irina: Flame retardancy afforded by polyaniline deposited on wood. J Appl Polym Sci 2007, 103, 24. <http://dx.doi.org/10.1002/app.23873>
  • Bhadra Sambhu, Singha Nikhil K, Khastgir Dipak: Dual functionality of PTSA as electrolyte and dopant in the electrochemical synthesis of polyaniline, and its effect on electrical properties. Polym Int 2007, 56, 919. <http://dx.doi.org/10.1002/pi.2225>
  • Gök Ayşegül, Omastová Mária, Prokeš Jan: Synthesis and characterization of red mud/polyaniline composites: Electrical properties and thermal stability. Euro Poly J 2007, 43, 2471. <http://dx.doi.org/10.1016/j.eurpolymj.2007.03.005>
  • Chen Chih-Yuan, Garnica-Rodriguez Jairo I., Duke Mikel C., Costa Roni F. Dalla, Dicks Andrew L., da Costa João C. Diniz: Nafion/polyaniline/silica composite membranes for direct methanol fuel cell application. J Power Sources - 2007, 166, 324. <http://dx.doi.org/10.1016/j.jpowsour.2006.12.102>
  • Shreepathi Subrahmanya, Van Hoang Hung, Holze Rudolf: Corrosion Protection Performance and Spectroscopic Investigations of Soluble Conducting Polyaniline-Dodecylbenzenesulfonate Synthesized via Inverse Emulsion Procedure. J Electrochem Soc 2007, 154, C67. <http://dx.doi.org/10.1149/1.2398815>
  • Konyushenko Elena N, Stejskal Jaroslav, Šeděnková Ivana, Trchová Miroslava, Sapurina Irina, Cieslar Miroslav, Prokeš Jan: Polyaniline nanotubes: conditions of formation. Polym Int 2006, 55, 31. <http://dx.doi.org/10.1002/pi.1899>
  • V. Blinova Natalia, Stejskal Jaroslav, Trchová Miroslava, Prokeš Jan: Polyaniline prepared in solutions of phosphoric acid: Powders, thin films, and colloidal dispersions. Poly 2006, 47, 42. <http://dx.doi.org/10.1016/j.polymer.2005.10.145>
  • Konyushenko Elena N., Stejskal Jaroslav, Trchová Miroslava, Hradil Jiří, Kovářová Jana, Prokeš Jan, Cieslar Miroslav, Hwang Jeong-Yuan, Chen Kuei-Hsien, Sapurina Irina: Multi-wall carbon nanotubes coated with polyaniline. Poly 2006, 47, 5715. <http://dx.doi.org/10.1016/j.polymer.2006.05.059>
  • Stejskal Jaroslav, Sapurina Irina, Trchová Miroslava, Konyushenko Elena N., Holler Petr: The genesis of polyaniline nanotubes. Poly 2006, 47, 8253. <http://dx.doi.org/10.1016/j.polymer.2006.10.007>
  • Šeděnková Ivana, Trchová Miroslava, Blinova Natalia V., Stejskal Jaroslav: In-situ polymerized polyaniline films. Preparation in solutions of hydrochloric, sulfuric, or phosphoric acid. This Solid Films 2006, 515, 1640. <http://dx.doi.org/10.1016/j.tsf.2006.05.038>
  • Sapurina I. Yu., Stejskal J., Trchová M., Hlavatá D., Biryulin Yu. F.: Organic Nanocolloidal Polyaniline Dispersions Containing Fullerene. Fullerene Nanot Carbon Nanostruct 2006, 14, 447. <http://dx.doi.org/10.1080/15363830600666126>
  • Kompan M. E., Sapurina I. Yu., Stejskal J.: Overcoming the low-dimension crisis in the active zone of fuel cells. Tech Phys Lett 2006, 32, 213. <http://dx.doi.org/10.1134/S1063785006030114>
  • Zabrodskiĭ A. G., Kompan M. E., Malyshkin V. G., Sapurina I. Yu.: Carbon supported polyaniline as anode catalyst: Pathway to platinum-free fuel cells. Tech Phys Lett 2006, 32, 758. <http://dx.doi.org/10.1134/S1063785006090070>
  • Sapurina Irina, Stejskal Jaroslav, Špírková Milena, Kotek Jiří, Prokeš Jan: Polyurethane latex modified with polyaniline. Synthetic Metal 2005, 151, 93. <http://dx.doi.org/10.1016/j.synthmet.2005.03.014>