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Pure Appl. Chem., 2006, Vol. 78, No. 2, pp. 209-214

http://dx.doi.org/10.1351/pac200678020209

Air-stable phosphine oxides as preligands for catalytic activation reactions of C-Cl, C-F, and C-H bonds

Lutz Ackermann, Robert Born, Julia H. Spatz, Andreas Althammer and Christian J. Gschrei

Ludwig-Maximilians-Universität München, Department Chemie und Biochemie, Butenandtstrasse 5-13, Haus F, 81377 München, Germany

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  • Jin Zhong, Li Yan-Jing, Ma Yong-Qiang, Qiu Ling-Ling, Fang Jian-Xin: Biphenyl-Based Diaminophosphine Oxides as Air-Stable Preligands for the Nickel-Catalyzed Kumada-Tamao-Corriu Coupling of Deactivated Aryl Chlorides, Fluorides, and Tosylates. Chemistry A European Journal 2012, 18, 446. <http://dx.doi.org/10.1002/chem.201103050>
  • Ackermann Lutz, Diers Emelyne, Manvar Atul: Ruthenium-Catalyzed C–H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles. Org Lett 2012, 120207111757000. <http://dx.doi.org/10.1021/ol3000876>
  • Gusarova Nina K., Arbuzova Svetlana N., Trofimov Boris A.: Novel general halogen-free methodology for the synthesis of organophosphorus compounds. PureAppl Chem 2012, 1. <http://dx.doi.org/10.1351/PAC-CON-11-07-11>
  • Ackermann Lutz, Punji Benudhar, Song Weifeng: User-Friendly [(Diglyme)NiBr2]-Catalyzed Direct Alkylations of Heteroarenes with Unactivated Alkyl Halides through CH Bond Cleavages. Synth Catal 2011, 353, 3325. <http://dx.doi.org/10.1002/adsc.201100487>
  • Achard Thierry, Lepronier Aymeric, Gimbert Yves, Clavier Hervé, Giordano Laurent, Tenaglia Alphonse, Buono Gérard: A Regio- and Diastereoselective Platinum-Catalyzed Tandem [2+1]/[3+2] Cycloaddition Sequence. Angew Chem 2011, 123, 3614. <http://dx.doi.org/10.1002/ange.201007992>
  • Achard Thierry, Lepronier Aymeric, Gimbert Yves, Clavier Hervé, Giordano Laurent, Tenaglia Alphonse, Buono Gérard: A Regio- and Diastereoselective Platinum-Catalyzed Tandem [2+1]/[3+2] Cycloaddition Sequence. Angew Chem Int Ed 2011, 50, 3552. <http://dx.doi.org/10.1002/anie.201007992>
  • Ackermann Lutz, Kapdi Anant R., Fenner Sabine, Kornhaaß Christoph, Schulzke Carola: Well-Defined Air-Stable Palladium HASPO Complexes for Efficient Kumada-Corriu Cross-Couplings of (Hetero)Aryl or Alkenyl Tosylates. Chem Eur J 2011, 17, 2965. <http://dx.doi.org/10.1002/chem.201002386>
  • Christiansen Andrea, Selent Detlef, Spannenberg Anke, Köckerling Martin, Reinke Helmut, Baumann Wolfgang, Jiao Haijun, Franke Robert, Börner Armin: Heteroatom-Substituted Secondary Phosphine Oxides (HASPOs) as Decomposition Products and Preligands in Rhodium-Catalysed Hydroformylation. Chemistry A European Journal 2011, 17, 2120. <http://dx.doi.org/10.1002/chem.201002823>
  • Martin David, Moraleda Delphine, Achard Thierry, Giordano Laurent, Buono Gérard: Assessment of the Electronic Properties of P ligands Stemming from Secondary Phosphine Oxides. Chemistry A European Journal 2011, 17, 12729. <http://dx.doi.org/10.1002/chem.201101663>
  • Shaikh Tanveer Mahamadali, Weng Chia-Ming, Hong Fung-E: Secondary phosphine oxides: Versatile ligands in transition metal-catalyzed cross-coupling reactions. Coord Rev 2011. <http://dx.doi.org/10.1016/j.ccr.2011.11.007>
  • Ackermann Lutz, Barfüsser Sebastian, Kornhaass Christoph, Kapdi Anant R.: C–H Bond Arylations and Benzylations on Oxazol(in)es with a Palladium Catalyst of a Secondary Phosphine Oxide. Org Lett 2011, 13, 3082. <http://dx.doi.org/10.1021/ol200986x>
  • Karanik Magdalena, Lesage Denis, Gimbert Yves, Nava Paola, Humbel Stéphane, Giordano Laurent, Buono Gérard, Tabet Jean-Claude: Do Platinum(II) and Palladium(II) Phosphinito Phosphinous Acids Generate the Same Type of Reactive Intermediate in Alkyne Coordination? A Gas-Phase Study with Phenylethyne and Propargyl Acetate. Organomettalics 2011, 110826163335088. <http://dx.doi.org/10.1021/om200234c>
  • Röhlich Christoph, Köhler Klaus: Macrocyclic Palladium(II) Complexes in CC Coupling Reactions: Efficient Catalysis by Controlled Temporary Release of Active Species. Synth Catal 2010, 352, 2263. <http://dx.doi.org/10.1002/adsc.201000458>
  • Christiansen Andrea, Li Chuanzhao, Garland Marc, Selent Detlef, Ludwig Ralf, Franke Robert, Börner Armin: Secondary Phosphane Oxides as Preligands in Rhodium-Catalyzed Hydroformylation. ChemCatChem 2010, 2, 1278. <http://dx.doi.org/10.1002/cctc.201000114>
  • Ackermann Lutz, Potukuchi Harish K., Kapdi Anant R., Schulzke Carola: Kumada-Corriu Cross-Couplings with 2-Pyridyl Grignard Reagents. Chem Eur J 2010, 16, 3300. <http://dx.doi.org/10.1002/chem.201000032>
  • Xie Lan-Gui, Wang Zhong-Xia: Nickel-Catalyzed Cross-Coupling of Non-Activated or Functionalized Aryl Halides with Aryl Grignard Reagents. Chem Eur J 2010, 16, 10332. <http://dx.doi.org/10.1002/chem.201001022>
  • Ackermann Lutz: Air-Stable Bifunctional HASPO Preligands for Metal-Catalyzed Cross-Couplings and Direct C-H Bond Arylations. Isr J Chem 2010, 50, 652. <http://dx.doi.org/10.1002/ijch.201000043>
  • Firouzabadi Habib, Iranpoor Nasser, Gholinejad Mohammad: 2-Aminophenyl diphenylphosphinite as an easily accessible ligand for heterogeneous palladium-catalyzed Suzuki–Miyaura reaction in water in the absence of any organic co-solvent. J Organomet Chem 2010, 695, 2093. <http://dx.doi.org/10.1016/j.jorganchem.2010.05.016>
  • Das Pankaj, Bora Utpal, Tairai Archana, Sharma Chandan: Triphenylphosphine chalcogenides as efficient ligands for room temperature palladium(II)-catalyzed Suzuki–Miyaura reaction. Tetrahetron Lett 2010, 51, 1479. <http://dx.doi.org/10.1016/j.tetlet.2010.01.032>
  • Ackermann Lutz: Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides. Chem Commun 2010, 46, 4866. <http://dx.doi.org/10.1039/c0cc00778a>
  • Ackermann Lutz, Potukuchi Harish Kumar: Regioselective syntheses of fully-substituted 1,2,3-triazoles: the CuAAC/C–H bond functionalization nexus. Org Biomol Chem 2010, 8, 4503. <http://dx.doi.org/10.1039/c0ob00212g>
  • Ackermann Lutz: Transition-metal-catalyzed direct arylations via C–H bond cleavages. Pure and App Chemis 2010, 1. <http://dx.doi.org/10.1351/PAC-CON-09-08-17>
  • Deng Guojun, Chen Wenwen, Li Chao-Jun: An Unusual Peroxide-Mediated Amination of Cycloalkanes with Nitroarenes. Adv Synth Catal 2009, 351, 353. <http://dx.doi.org/10.1002/adsc.200800689>
  • Ackermann Lutz, Vicente Rubén, Kapdi Anant R.: Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage. Angew Chem Int Ed 2009, 48, 9792. <http://dx.doi.org/10.1002/anie.200902996>
  • Braun Leonie, Liptau Patrick, Kehr Gerald, Ugolotti Juri, Fr?hlich Roland, Erker Gerhard: Bis(diphenylphosphino)acetonitrile: Synthesis, ligand properties and application in catalytic carbon?carbon coupling. Dalton Trans 2007, 1409. <http://dx.doi.org/10.1039/b616847g>
  • Ackermann Lutz, Born Robert, Spatz Julia H., Althammer Andreas, Gschrei Christian J.: Air-Stable Phosphine Oxides as Preligands for Catalytic Activation Reactions of C—Cl, C—F, and C—H Bonds. ChemInform 2006, 37. <http://dx.doi.org/10.1002/chin.200630281>
  • Ackermann Lutz, Althammer Andreas: Air-Stable PinP(O)H as Preligand for Palladium-Catalyzed Kumada Couplings of Unactivated Tosylates. Org Lett 2006, 8, 3457. <http://dx.doi.org/10.1021/ol061116o>