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Pure Appl. Chem., 2006, Vol. 78, No. 2, pp. 215-229

http://dx.doi.org/10.1351/pac200678020215

Toward an understanding of the factors responsible for the 1,2-migration of alkyl groups in borate complexes

Varinder K. Aggarwal, Guang Yu Fang, Xavier Ginesta, Dean M. Howells and Mirko Zaja

School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS, UK

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  • Curran Dennis P., Solovyev Andrey, Makhlouf Brahmi Malika, Fensterbank Louis, Malacria Max, Lacôte Emmanuel: Komplexe von N-heterocyclischen Carbenen mit Boranen: Synthese und Reaktionen. angew chemie 2011, 123, 10476. <http://dx.doi.org/10.1002/ange.201102717>
  • Curran Dennis P., Solovyev Andrey, Makhlouf Brahmi Malika, Fensterbank Louis, Malacria Max, Lacôte Emmanuel: Synthesis and Reactions of N-Heterocyclic Carbene Boranes. Angew Chem Int E 2011, 50, 10294. <http://dx.doi.org/10.1002/anie.201102717>
  • Elford Tim G., Nave Stefan, Sonawane Ravindra P., Aggarwal Varinder K.: Total Synthesis of (+)-Erogorgiaene Using Lithiation–Borylation Methodology, and Stereoselective Synthesis of Each of Its Diastereoisomers. S J Am Chem Soc 2011, 133, 16798. <http://dx.doi.org/10.1021/ja207869f>
  • Larouche-Gauthier Robin, Fletcher Catherine J., Couto Irantzu, Aggarwal Varinder K.: Use of alkyl 2,4,6-triisopropylbenzoates in the asymmetric homologation of challenging boronic esters. Chem Commn 2011, 47, 12592. <http://dx.doi.org/10.1039/c1cc14469c>
  • Dureen Meghan A., Stephan Douglas W.: Reactions of Boron Amidinates with CO2 and CO and Other Small Molecules. J Am Chem Soc 2010, 132, 13559. <http://dx.doi.org/10.1021/ja1064153>
  • Thomas Stephen P., French Rosalind M., Jheengut Vishal, Aggarwal Varinder K.: Homologation and alkylation of boronic esters and boranes by 1,2-metallate rearrangement of boron ate complexes. Chem Record 2009, 9, 24. <http://dx.doi.org/10.1002/tcr.20168>
  • Crudden Cathleen M., Glasspoole Ben W., Lata Christopher J.: Expanding the scope of transformations of organoboron species: carbon–carbon bond formation with retention of configuration. Chem Commun 2009, 6704. <http://dx.doi.org/10.1039/b911537d>
  • Stymiest Jake L., Bagutski Viktor, French Rosalind M., Aggarwal Varinder K.: Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols. Nature (London) 2008, 456, 778. <http://dx.doi.org/10.1038/nature07592>
  • Fang Guang Yu, Aggarwal Varinder K.: Asymmetric Synthesis of α-Substituted Allyl Boranes and Their Application in the Synthesis of Iso-agatharesinol. Angew Chem 2007, 119, 363. <http://dx.doi.org/10.1002/ange.200603659>
  • Dutheuil Guillaume, Mahmood Adeem, Aggarwal Varinder K., Stymiest Jake L.: Lithiated Carbamates: Chiral Carbenoids for Iterative Homologation of Boranes and Boronic Esters. Angew Chem 2007, 119, 7635. <http://dx.doi.org/10.1002/ange.200702146>
  • Fang Guang Yu, Aggarwal Varinder K.: Asymmetric Synthesis of α-Substituted Allyl Boranes and Their Application in the Synthesis of Iso-agatharesinol. Angew Chem Int Ed 2007, 46, 359. <http://dx.doi.org/10.1002/anie.200603659>
  • Stymiest Jake L., Dutheuil Guillaume, Mahmood Adeem, Aggarwal Varinder K.: Lithiated Carbamates: Chiral Carbenoids for Iterative Homologation of Boranes and Boronic Esters. Angew Chem Int Ed 2007, 46, 7491. <http://dx.doi.org/10.1002/anie.200702146>
  • Aggarwal Varinder K., Fang Guang Yu, Ginesta Xavier, Howells Dean M., Zaja Mirko: Toward an Understanding of the Factors Responsible for the 1,2-Migration of Alkyl Groups in Borate Complexes. ChemInform 2006, 37. <http://dx.doi.org/10.1002/chin.200626277>