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Pure Appl. Chem., 2006, Vol. 78, No. 2, pp. 341-349

doi:10.1351/pac200678020341

Development of palladium catalysts for asymmetric hydroamination reactions*

King Kuok (Mimi) Hii

Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London SW7 2AZ, UK


Abstract: Our development of dicationic palladium(II) complexes for asymmetric hydroamination reactions, particularly the aza-Michael addition, is reviewed.

Keywords: alkenes; amines; asymmetric catalysis; hydroamination; palladium.

*Pure Appl. Chem. 78, 197-523. An issue of reviews and research papers based on lectures presented at the 13th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-13), Geneva, Switzerland, 17-21 July 2005.