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Pure Appl. Chem., 2006, Vol. 78, No. 2, pp. 469-476

http://dx.doi.org/10.1351/pac200678020469

Connecting catalytic cycles by organometallic transformations in situ: Novel perspectives in the olefin metathesis field

Bernd Schmidt

Department of Chemistry, Organic Chemistry, University of Dortmund, Otto-Hahn-Strasse 6, D-44227 Dortmund, Germany

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  • Schmidt Bernd, Kunz Oliver: One-Flask Tethered Ring Closing Metathesis-Electrocyclic Ring Opening for the Highly Stereoselective Synthesis of Conjugated Z/E-Dienes. Eur J Org 2012, 2012, 1008. <http://dx.doi.org/10.1002/ejoc.201101497>
  • Ashikari Yosuke, Nokami Toshiki, Yoshida Jun-ichi: Oxidative Hydroxylation Mediated by Alkoxysulfonium Ions. Org Lett 2012, 14, 938. <http://dx.doi.org/10.1021/ol203467v>
  • Ascic Erhad, Jensen Jakob F., Nielsen Thomas E.: Synthesis of Heterocycles through a Ruthenium-Catalyzed Tandem Ring-Closing Metathesis/Isomerization/N-Acyliminium Cyclization Sequence. Angew Chem 2011, 123, 5294. <http://dx.doi.org/10.1002/ange.201100417>
  • Ascic Erhad, Jensen Jakob F., Nielsen Thomas E.: Synthesis of Heterocycles through a Ruthenium-Catalyzed Tandem Ring-Closing Metathesis/Isomerization/N-Acyliminium Cyclization Sequence. Angew Chem Int Ed 2011, 50, 5188. <http://dx.doi.org/10.1002/anie.201100417>
  • Ding Fu, Doorslaer Sabine Van, Cool Peggie, Verpoort Francis: Olefin isomerization reactions catalyzed by ruthenium hydrides bearing Schiff base ligands. Appl Organometal Chem 2011, 25, 601. <http://dx.doi.org/10.1002/aoc.1808>
  • Ashikari Yosuke, Nokami Toshiki, Yoshida Jun-ichi: Integrated Electrochemical–Chemical Oxidation Mediated by Alkoxysulfonium Ions. J Am Chcm Soc 2011, 133, 11840. <http://dx.doi.org/10.1021/ja202880n>
  • Schmidt Bernd, Krehl Stefan: A single precatalyst tandem RCM–allylic oxidation sequence. Chem Commun 2011, 47, 5879. <http://dx.doi.org/10.1039/c1cc11347j>
  • Brown Lindsay, McGonagle Fiona I., Cooke Andrew, Sutherland Andrew: A three-step tandem process for the synthesis of bicyclic γ-lactams. Org Biomol Chem 2010, 8, 3418. <http://dx.doi.org/10.1039/c004695g>
  • Song Ren-Jie, Liu Yu, Li Rong-Jiang, Li Jin-Heng: Selective synthesis of 3-methyleneindolin-2-ones by one-pot multicatalytic processes. Tetrahetron Lett 2009, 50, 3912. <http://dx.doi.org/10.1016/j.tetlet.2009.04.066>
  • Rowley Christopher N., Woo Tom K.: Computational design of ruthenium hydride olefin-hydrogenation catalysts containing hemilabile ligands1,2. Can J Chem 2009, 87, 1030. <http://dx.doi.org/10.1139/V09-077>
  • Plumet Joaquín, Aljarilla Ana: Tandem Metathesis Reactions Cascade Ring-Opening Metathesis (ROM)-Ring-Closing Metathesis (RCM)-Cross Metathesis Dimerization (CMD) in 7-Oxabicyclo[2.2.1]hept-5-one (7-Oxanorbornene) Derivatives. HETEROCYLES 2009, 77, 1333. <http://dx.doi.org/10.3987/COM-08-S(F)45>
  • Leogane Olivier, Lebel Hélène: One-Pot Multicomponent Synthesis of Indoles from 2-Iodobenzoic Acid. Angew Chem 2008, 120, 356. <http://dx.doi.org/10.1002/ange.200703671>
  • Leogane Olivier, Lebel Hélène: One-Pot Multicomponent Synthesis of Indoles from 2-Iodobenzoic Acid. Angew Chem Int Ed 2008, 47, 350. <http://dx.doi.org/10.1002/anie.200703671>
  • Schmidt Bernd, Biernat Anne: The Tandem Ring‐Closing Metathesis–Isomerization Approach to 6‐Deoxyglycals. Chem Eur J 2008, 14, 6135. <http://dx.doi.org/10.1002/chem.200800567>
  • Schmidt Bernd, Biernat Anne: Synthesis of 3-Deoxy Glycals via Tandem Metathesis Sequences and Their Use in an Intermolecular Heck Arylation. Eur J Org Chem 2008, 2008, 5764. <http://dx.doi.org/10.1002/ejoc.200800824>
  • Murelli Ryan P., Catalán Silvia, Gannon Michael P., Snapper Marc L.: Ruthenium-catalyzed tandem enyne-cross metathesis–cyclopropanation: three-component access to vinyl cyclopropanes. Tetrahetron Lett 2008, 49, 5714. <http://dx.doi.org/10.1016/j.tetlet.2008.07.119>
  • Appukkuttan Prasad, Dehaen Wim, Van der Eycken Erik: Microwave-Assisted Transition-Metal-Catalyzed Synthesis of N-Shifted and Ring-Expanded Buflavine Analogues. Chem Eur J 2007, 13, 6452. <http://dx.doi.org/10.1002/chem.200700177>
  • Schmidt Bernd: Connecting Catalytic Cycles by Organometallic Transformations in situ: Novel Perspectives in Olefin Metathesis. ChemInform 2006, 37. <http://dx.doi.org/10.1002/chin.200630277>
  • Schmidt Bernd, Staude Lucia: Unexpected transfer hydrogenation of C–C-double bonds during Tandem-RCM-isomerization reactions. J Organomet Chem 2006, 691, 5218. <http://dx.doi.org/10.1016/j.jorganchem.2006.07.011>
  • Dragutan Valerian, Dragutan Ileana: A resourceful new strategy in organic synthesis: Tandem and stepwise metathesis/non-metathesis catalytic processes. J Organomet Chem 2006, 691, 5129. <http://dx.doi.org/10.1016/j.jorganchem.2006.08.012>
  • Edlin Chris D., Faulkner James, Fengas David, Helliwell Madeleine, Knight Christopher K., House David, Parker Jeremy, Preece Ian, Quayle Peter, Raftery James: Toward catalyst economy: A programmed approach to the synthesis of bicyclic lactones and lactams. J Organomet Chem 2006, 691, 5375. <http://dx.doi.org/10.1016/j.jorganchem.2006.08.017>
  • Coyanis E. Mabel, Panayides Jenny-Lee, Fernandes Manuel A., de Koning Charles B., van Otterlo Willem A.L.: Ring-closing metathesis for the synthesis of substituted indenols, indenones, indanones and indenes: Tandem RCM-dehydrogenative oxidation and RCM-formal redox isomerization. J Organomet Chem 2006, 691, 5222. <http://dx.doi.org/10.1016/j.jorganchem.2006.08.074>