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Pure Appl. Chem., 2006, Vol. 78, No. 4, pp. 847-853

doi:10.1351/pac200678040847

Synthesis and properties of phenyleneethynylene-based dendritic structures*

Jean-François Nierengarten

Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne,31077 Toulouse Cédex 4, France


Abstract: In this paper, we report on our ongoing progress on the synthesis and study of branched molecular architectures with a conjugated scaffold. Specifically, new conjugated dendrons incorporating 1,2,4-triethynyl-phenyl units have been developed and used as building blocks for the synthesis of isomeric branched conjugated systems and light-harvesting dendrimers.

Keywords: alkynes; conjugation; cross-coupling; dendrimers; fullerenes.

*Paper based on a presentation at the 11th International Symposium on Novel Aromatic Compounds (ISNA-11), St. John's, Newfoundland, Canada, 14-18 August 2005. Other presentations are published in this issue, pp. 685-888..