Pure Appl. Chem., 2007, Vol. 79, No. 2, pp. 163-172
doi:10.1351/pac200779020163
Recent results toward the stereoselective synthesis of biologically active natural products*
Luiz C. Dias, Luciana G. de Oliveira, and Paulo R. R. Meira
Instituto de Química, Universidade Estadual de Campinas, UNICAMP, C.P. 6154, CEP 13084-971, Campinas, São Paulo, Brazil
Abstract:
This paper describes the convergent and stereocontrolled asymmetric total synthesis of (+)-crocacins C and D, potent inhibitors of animal cell cultures and several yeasts and fungi, and (-)-callystatin A, a potent antitumor polyketide.
Keywords: antitumor compound; diastereocontrol; natural product synthesis; polyketides.
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