Pure Appl. Chem., 2009, Vol. 81, No. 11, pp. 2115-2122
doi:10.1351/PAC-CON-08-10-14
Published online 2009-11-04
Role of reaction media in "green" radiation-induced polymerization of white phosphorus
Abstract:
Phosphorus-containing polymers were synthesized using a "green" radiation-induced reaction at room temperature in the presence of ionic liquids (ILs). The nature of ILs allowed us to adjust the properties of reaction media (dimethyl sulfoxide, DMSO–benzene solvents). The effects of various factors on the efficiency of the synthesis of phosphorus-containing polymers are discussed.
Keywords
elemental phosphorus; imidazolium; ionic liquids; phosphonium; phosphorus-containing polymers; radiation-induced polymerization.
Conference
Full text is not freely available, please see subscription information for options to obtain it.