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Pure Appl. Chem., 2009, Vol. 81, No. 4, pp. 597-614

http://dx.doi.org/10.1351/PAC-CON-08-11-03

Divalent carbon(0) compounds

Gernot Frenking1 and Ralf Tonner2

1 Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany
2 Centre for Theoretical Chemistry and Physics, New Zealand Institute for Advanced Study; Massey University Albany, Private Bag 102904, North Shore City, 0745 Auckland, New Zealand

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  • Takagi Nozomi, Tonner Ralf, Frenking Gernot: Carbodiphosphorane Analogues E(PPh3)2 with E=C-Pb: A Theoretical Study with Implications for Ligand Design. Chemistry A European Journal 2012, 18, 1772. <http://dx.doi.org/10.1002/chem.201100494>
  • Esterhuysen Catharine, Frenking Gernot: Distinguishing Carbones from Allenes by Complexation to AuCl. Chemistry A European Journal 2011, 17, 9944. <http://dx.doi.org/10.1002/chem.201101213>
  • Petz Wolfgang, Neumüller Bernhard: Reaction of C(PPh3)2 with MI2 Compounds (M = Zn, Cd) - Formation and Crystal Structures of [I2Zn{C(PPh3)2}], [(I2Cd{C(PPh3)2})2] and the Salt-Like Compounds (HC{PPh3}2)[MI3(THF)] and (HC{PPh3}2)2[ZnI4]. Euro J Inorg Chem 2011, 2011, 4889. <http://dx.doi.org/10.1002/ejic.201100646>
  • Tonner Ralf, Frenking Gernot: Carbodicarbenes-divalent carbon(0) compounds exhibiting carbon-carbon donor-acceptor bonds. WIREs Comput Mol Sci 2011, 1, 869. <http://dx.doi.org/10.1002/wcms.53>
  • Petz Wolfgang, Dehnicke Kurt, Neumüller Bernhard: About the Reaction of BeCl2 with the Carbodiphosphorane Addition Compound O2C←C(PPh3)2 and its Hydrolysis Product Ph3PCHP(O)Ph2. Z anorg allg Chem 2011, 637, 1761. <http://dx.doi.org/10.1002/zaac.201100293>
  • Petz Wolfgang, Dehnicke Kurt, Holzmann Nicole, Frenking Gernot, Neumüller Bernhard: The Reaction of BeCl2 with Carbodiphosphorane C(PPh3)2; Experimental and Theoretical Studies. Z anorg allg Chem 2011, 637, 1702. <http://dx.doi.org/10.1002/zaac.201100328>
  • Takagi Nozomi, Frenking Gernot: Divalent Pb(0) compounds. Theor Chem Acc 2011, 129, 615. <http://dx.doi.org/10.1007/s00214-011-0909-9>
  • DeHope Alan, Donnadieu Bruno, Bertrand Guy: Grubbs and Hoveyda-type ruthenium complexes bearing a cyclic bent-allene. J Organomet Chem 2011, 696, 2899. <http://dx.doi.org/10.1016/j.jorganchem.2011.03.010>
  • Patel Dhilon S., Bharatam Prasad V.: To Bend or Not to Bend! The Dilemma of Allenes. J Org Chem 2011, 76, 2558. <http://dx.doi.org/10.1021/jo102432a>
  • Patel Dhilon S., Bharatam Prasad V.: Divalent N(I) Compounds with Two Lone Pairs on Nitrogen. J Phys Chem A 2011, 115, 7645. <http://dx.doi.org/10.1021/jp111017u>
  • Martin David, Melaimi Mohand, Soleilhavoup Michele, Bertrand Guy: A Brief Survey of Our Contribution to Stable Carbene Chemistry. Organomettalics 2011, 30, 5304. <http://dx.doi.org/10.1021/om200650x>
  • Martin David, Soleilhavoup Michele, Bertrand Guy: Stable singlet carbenes as mimics for transition metal centers. Chem Sci 2011, 2, 389. <http://dx.doi.org/10.1039/c0sc00388c>
  • Melaimi Mohand, Soleilhavoup Michèle, Bertrand Guy: Stabile cyclische Carbene und verwandte Spezies jenseits der Diaminocarbene. Angew Chem 2010, 122, 8992. <http://dx.doi.org/10.1002/ange.201000165>
  • Guisado-Barrios Gregorio, Bouffard Jean, Donnadieu Bruno, Bertrand Guy: Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs). Angew Chem 2010, 122, 4869. <http://dx.doi.org/10.1002/ange.201001864>
  • Klein Susanne, Frenking Gernot: Carbodiylide C(ECp*)2 (E=B-Tl): eine weitere Klasse theoretisch vorhergesagter Kohlenstoff(0)-Verbindungen. Angew Chem 2010, 122, 7260. <http://dx.doi.org/10.1002/ange.201002773>
  • Kinjo Rei, Donnadieu Bruno, Bertrand Guy: Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN+.). Angew Chem 2010, 122, 6066. <http://dx.doi.org/10.1002/ange.201002889>
  • Melaimi Mohand, Soleilhavoup Michèle, Bertrand Guy: Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes. Angew Chem Int Ed 2010, 49, 8810. <http://dx.doi.org/10.1002/anie.201000165>
  • Guisado-Barrios Gregorio, Bouffard Jean, Donnadieu Bruno, Bertrand Guy: Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs). Angew Chem Int Ed 2010, n/a. <http://dx.doi.org/10.1002/anie.201001864>
  • Klein Susanne, Frenking Gernot: Carbodiylides C(ECp*)2 (E=B-Tl): Another Class of Theoretically Predicted Divalent Carbon(0) Compounds. Angew Chem Int Ed 2010, 49, 7106. <http://dx.doi.org/10.1002/anie.201002773>
  • Kinjo Rei, Donnadieu Bruno, Bertrand Guy: Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN+.). Angew Chem Int Ed 2010, n/a. <http://dx.doi.org/10.1002/anie.201002889>
  • Klein Susanne, Tonner Ralf, Frenking Gernot: Carbodicarbenes and Related Divalent Carbon(0) Compounds. Chem Eur J 2010, 16, 10160. <http://dx.doi.org/10.1002/chem.201000174>
  • Takagi Nozomi, Shimizu Takayasu, Frenking Gernot: Divalent E(0) Compounds (E=Si-Sn). Chem Eur J 2009, 15, 8593. <http://dx.doi.org/10.1002/chem.200901401>
  • Petz Wolfgang, Öxler Florian, Neumüller Bernhard, Tonner Ralf, Frenking Gernot: Carbodiphosphorane C(PPh3)2 as a Single and Twofold Lewis Base with Boranes: Synthesis, Crystal Structures and Theoretical Studies on [H3B{C(PPh3)2}] and [{(μ-H)H4B2}{C(PPh3)2}]+ . Eur J Inorg Chem 2009, 2009, 4507. <http://dx.doi.org/10.1002/ejic.200900691>
  • Dyker C. Adam, Bertrand Guy: Chemical bonding: Rethinking carbon. Nature Chem 2009, 1, 265. <http://dx.doi.org/10.1038/nchem.265>