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Pure Appl. Chem., 2010, Vol. 82, No. 2, pp. 483-491

http://dx.doi.org/10.1351/PAC-REP-08-04-03

Published online 2009-11-18

Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)

Aubrey D. Jenkins1, Richard G. Jones2* and Graeme Moad3*

1 22A North Court, Hassocks, West Sussex, BN6 8JS, UK
2 University of Kent, Canterbury, Kent CT2 7NH, UK
3 CSIRO Molecular and Health Technologies, Bag 10, Clayton South, VIC 3169, Australia

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  • Brusseau Ségolène, D’Agosto Franck, Magnet Stéphanie, Couvreur Laurence, Chamignon Cécile, Charleux Bernadette: Nitroxide-Mediated Copolymerization of Methacrylic Acid and Sodium 4-Styrenesulfonate in Water Solution and One-Pot Synthesis of Amphiphilic Block Copolymer Nanoparticles. Macro­molecules 2011, 44, 5590. <http://dx.doi.org/10.1021/ma2008282>
  • Zhang Wenjing, D’Agosto Franck, Boyron Olivier, Rieger Jutta, Charleux Bernadette: One-Pot Synthesis of Poly(methacrylic acid-co-poly(ethylene oxide) methyl ether methacrylate)-b-polystyrene Amphiphilic Block Copolymers and Their Self-Assemblies in Water via RAFT-Mediated Radical Emulsion Polymerization. A Kinetic Study. Macro­molecules 2011, 44, 7584. <http://dx.doi.org/10.1021/ma201515n>
  • Zehm Daniel, Laschewsky André, Liang Hua, Rabe Jürgen P.: Straightforward Access to Amphiphilic Dual Bottle Brushes by Combining RAFT, ATRP, and NMP Polymerization in One Sequence. Macro­molecules 2011, 44, 9635. <http://dx.doi.org/10.1021/ma2015613>
  • Hornung Christian H., Guerrero-Sanchez Carlos, Brasholz Malte, Saubern Simon, Chiefari John, Moad Graeme, Rizzardo Ezio, Thang San H.: Controlled RAFT Polymerization in a Continuous Flow Microreactor. Org Process Res Dev 2011, 15, 593. <http://dx.doi.org/10.1021/op1003314>
  • Beija Mariana, Marty Jean-Daniel, Destarac Mathias: Thermoresponsive poly(N-vinyl caprolactam)-coated gold nanoparticles: sharp reversible response and easy tunability. Chem Commun 2011, 47, 2826. <http://dx.doi.org/10.1039/c0cc05184e>
  • Moad Graeme, Chen Ming, Häussler Matthias, Postma Almar, Rizzardo Ezio, Thang San H.: Functional polymers for optoelectronic applications by RAFT polymerization. Polym Chem 2011, 2, 492. <http://dx.doi.org/10.1039/c0py00179a>
  • Chen Ming, Häussler Matthias, Moad Graeme, Rizzardo Ezio: Block copolymers containing organic semiconductor segments by RAFT polymerization. Biomol Chem 2011, 9, 6111. <http://dx.doi.org/10.1039/c1ob05276d>
  • Girard Etienne, Tassaing Thierry, Marty Jean-Daniel, Destarac Mathias: Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide. Polym Chem 2011, 2, 2222. <http://dx.doi.org/10.1039/c1py00209k>
  • Destarac Mathias, Sandeau Aurélie, Mazières Stéphane, Vergelati Caroll, Corriol Cécile: Dixanthate-terminated poly(butylene terephthalate). A novel RAFT/MADIX agent for the synthesis of well-defined triblock copolymers resulting from consecutive step- and chain-growth polymerization processes. Polym Chem 2011, 2, 2490. <http://dx.doi.org/10.1039/c1py00270h>
  • Chen Xiaoping, Ding Keyang, Ayres Neil: Investigation into fiber formation in N-alkyl urea peptoid oligomers and the synthesis of a water-soluble PEG/N-alkyl urea peptoid oligomer conjugate. Polym Chem 2011, 2, 2635. <http://dx.doi.org/10.1039/c1py00284h>
  • Chen Ming, Moad Graeme, Rizzardo Ezio: A Potential New RAFT - Click Reaction or a Cautionary Note on the Use of Diazomethane to Methylate RAFT-synthesized Polymers. Aust J Chem 2011, 64, 433. <http://dx.doi.org/10.1071/CH10471>
  • Ayres Neil: Atom Transfer Radical Polymerization: A Robust and Versatile Route for Polymer Synthesis. Polymer Revs 2011, 51, 138. <http://dx.doi.org/10.1080/15583724.2011.566402>
  • Grubbs Robert B.: Nitroxide-Mediated Radical Polymerization: Limitations and Versatility. Polymer Revs 2011, 51, 104. <http://dx.doi.org/10.1080/15583724.2011.566405>
  • Shipp Devon A.: Reversible-Deactivation Radical Polymerizations. Polymer Revs 2011, 51, 99. <http://dx.doi.org/10.1080/15583724.2011.566406>
  • Destarac Mathias: On the Critical Role of RAFT Agent Design in Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization. Polymer Revs 2011, 51, 163. <http://dx.doi.org/10.1080/15583724.2011.568130>
  • Gregory Andrew, Stenzel Martina H: The use of reversible addition fragmentation chain transfer polymerization for drug delivery systems. Expert Opin Drug Deliv 2011, 8, 237. <http://dx.doi.org/10.1517/17425247.2011.548381>
  • Hojjati Behnaz, Charpentier Paul A.: Synthesis of TiO2-polymer nanocomposite in supercritical CO2 via RAFT polymerization. Polymer 2010, 51, 5345. <http://dx.doi.org/10.1016/j.polymer.2010.09.050>
  • Zhao Yulai, Wang Li, Xiao Anguo, Yu Haojie: The synthesis of modified polyethylene via coordination polymerization followed by ATRP, RAFT, NMRP or ROP. Prog Polym Sci 2010, 35, 1195. <http://dx.doi.org/10.1016/j.progpolymsci.2010.05.002>
  • Patra Braja N., Rayeroux David, Lacroix-Desmazes Patrick: Synthesis of cationic amphiphilic diblock copolymers of poly(vinylbenzyl triethylammonium chloride) and polystyrene by reverse iodine transfer polymerization (RITP). React & Funct Polym 2010, 70, 408. <http://dx.doi.org/10.1016/j.reactfunctpolym.2010.03.006>
  • D'Agosto Franck, Boisson Christophe: A RAFT Analogue Olefin Polymerization Technique Using Coordination Chemistry. Aust J Chem 2010, 63, 1155. <http://dx.doi.org/10.1071/CH10098>
  • Moad Graeme, Rizzardo Ezio, Thang San H.: Living Radical Polymerization by the RAFT Process – A Second Update. Aust J Chem 2009, 62, 1402. <http://dx.doi.org/10.1071/CH09311>