Pure Appl. Chem., 2012, Vol. 84, No. 8, pp. 1771-1784
Published online 2012-04-27
From molecular catalysts to nanostructured materials skeleton catalysts
Abstract: Molecular transformations using Au, Pd, and Cu nanoporous skeleton catalysts and the reactivity difference between those catalysts and the corresponding well-known homogeneous molecular catalysts are described. Nanoporous skeleton catalysts (e.g., PdNPore) can be fabricated through dealloying of the corresponding Pd-containing alloy PdxM1yM2z.
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