Pure and Applied Chemistry - ASAP Articles http://www.iupac.org/publications/pac/ Articles published ahead of print in Pure and Applied Chemistry. en A unique, two-component sensing system for fluorescence detection of glucose and other carbohydrates David B. Cordes and Bakthan Singaram Wed, 02 May 2012 23:06:04 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-36 http://dx.doi.org/10.1351/PAC-CON-11-10-36 New strategies for natural products containing chroman spiroketals Jason C. Green, G. Leslie Burnett, IV and Thomas R. R. Pettus Wed, 02 May 2012 23:03:47 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-34 http://dx.doi.org/10.1351/PAC-CON-11-10-34 Total synthesis of gelsemoxonine Jun Shimokawa, Takaaki Harada, Satoshi Yokoshima and Tohru Fukuyama Wed, 02 May 2012 23:01:15 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-25 http://dx.doi.org/10.1351/PAC-CON-11-10-25 Practical iron-catalyzed atom/group transfer and insertion reactions Toby Wai-Shan Chow, Guo-Qiang Chen, Yungen Liu, Cong-Ying Zhou and Chi-Ming Che Wed, 02 May 2012 22:59:03 +0100 http://dx.doi.org/10.1351/PAC-CON-11-11-08 http://dx.doi.org/10.1351/PAC-CON-11-11-08 Heterometallic cubane-type clusters containing group 13 and 16 elements K. Geetharani, Shubhankar Kumar Bose and Sundargopal Ghosh Sun, 29 Apr 2012 23:15:28 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-17 http://dx.doi.org/10.1351/PAC-CON-11-10-17 Bioactive cubitane diterpenoids from a Colombian gorgonian species of the genus Eunicea Xiaomei Wei, Karinel Nieves and Abimael D. Rodríguez Sun, 29 Apr 2012 23:08:27 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-20 http://dx.doi.org/10.1351/PAC-CON-11-10-20 Progress toward red and near-infrared (NIR) emitting saccharide sensors Martha Sibrian-Vazquez, Jorge O. Escobedo, Mark Lowry and Robert M. Strongin Sun, 29 Apr 2012 23:03:42 +0100 http://dx.doi.org/10.1351/PAC-CON-11-11-06 http://dx.doi.org/10.1351/PAC-CON-11-11-06 First total synthesis of the (±)-2-methoxy-6-heptadecynoic acid and related 2-methoxylated analogs as effective inhibitors of the Leishmania topoisomerase IB enzyme Néstor M. Carballeira, Michelle Cartagena, Fengyu Li, Zhongfang Chen, Christopher F. Prada, Estefania Calvo-Alvarez, Rosa M. Reguera and Rafael Balaña-Fouce Sun, 29 Apr 2012 22:54:34 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-21 http://dx.doi.org/10.1351/PAC-CON-11-10-21 N-Heterocyclic carbene copper-catalyzed carboxylation of C-B and C-H bonds with carbon dioxide Liang Zhang and Zhaomin Hou Sun, 29 Apr 2012 21:57:10 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-33 http://dx.doi.org/10.1351/PAC-CON-11-10-33 Synthesis of copolymers of ethylene and (meth)acrylates or styrene by an original dual radical/catalytic mechanism Alexandra Leblanc, Jean-Pierre Broyer, Christophe Boisson, Roger Spitz and Vincent Monteil Sun, 29 Apr 2012 21:51:20 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-05 http://dx.doi.org/10.1351/PAC-CON-11-10-05 Guidelines for reporting of phase equilibrium measurements (IUPAC Recommendations 2012) Robert D. Chirico, Theodoor W. de Loos, Jürgen Gmehling, Anthony R. H. Goodwin, Sumnesh Gupta, William M. Haynes, Kenneth N. Marsh, Vicente Rives, James D. Olson, Calvin Spencer, Joan F. Brennecke and J. P. Martin Trusler Fri, 27 Apr 2012 08:53:30 +0100 http://dx.doi.org/10.1351/PAC-REC-11-05-02 http://dx.doi.org/10.1351/PAC-REC-11-05-02 Synthesis of myxobacteria metabolites Stephen L. Birkett, Darran A. Loits, Samantha Wimala and Mark A. Rizzacasa Fri, 27 Apr 2012 08:50:19 +0100 http://dx.doi.org/10.1351/PAC-CON-11-11-19 http://dx.doi.org/10.1351/PAC-CON-11-11-19 From molecular catalysts to nanostructured materials skeleton catalysts Naoki Asao, Tienan Jin, Shinya Tanaka and Yoshinori Yamamoto Fri, 27 Apr 2012 08:47:18 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-28 http://dx.doi.org/10.1351/PAC-CON-11-10-28 Antiproliferative withanolides from the Solanaceae: A structure–activity study Huaping Zhang, Abbas K. Samadi, Mark S. Cohen and Barbara N. Timmermann Sun, 15 Apr 2012 22:01:16 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-08 http://dx.doi.org/10.1351/PAC-CON-11-10-08 Recent insights into natural venoms Daisuke Uemura, Chunguang Han, Novriyandi Hanif, Toshiyasu Inuzuka, Norihito Maru and Hirokazu Arimoto Mon, 09 Apr 2012 19:18:59 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-32 http://dx.doi.org/10.1351/PAC-CON-11-09-32 Pulsed chronopotentiometric membrane electrodes based on plasticized poly(vinyl chloride) with covalently bound ferrocene functionalities as solid contact transducer Marcin Pawlak, Ewa Grygolowicz-Pawlak and Eric Bakker Sun, 08 Apr 2012 23:55:04 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-23 http://dx.doi.org/10.1351/PAC-CON-11-09-23 Cauliflower polyaniline/multiwalled carbon nanotube electrode and its applications to hydrogen peroxide and glucose detection* Sujittra Poorahong, Chongdee Thammakhet, Panote Thavarungkul and Proespichaya Kanatharana Sat, 07 Apr 2012 10:53:49 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-07 http://dx.doi.org/10.1351/PAC-CON-11-10-07 Influence of the difluoromethylene group (CF2) on the conformation and properties of selected organic compounds David O'Hagan, Yi Wang, Maciej Skibinski and Alexandra M. Z. Slawin Sat, 07 Apr 2012 10:51:14 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-26 http://dx.doi.org/10.1351/PAC-CON-11-09-26 Exploring metal-driven stereoselectivity of glycopeptides by free-energy calculations Adriana Pietropaolo Sat, 07 Apr 2012 10:49:15 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-33 http://dx.doi.org/10.1351/PAC-CON-11-09-33 Synthesis and biological activities of chaetocin and its derivatives Mikiko Sodeoka, Kosuke Dodo, Yuou Teng, Katsuya Iuchi, Yoshitaka Hamashima, Eriko Iwasa and Shinya Fujishiro Mon, 02 Apr 2012 21:16:00 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-31 http://dx.doi.org/10.1351/PAC-CON-11-10-31 Synthesis of saxitoxins Osamu Iwamoto, Takafumi Akimoto and Kazuo Nagasawa Mon, 02 Apr 2012 21:12:29 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-10 http://dx.doi.org/10.1351/PAC-CON-11-09-10 Bioorganic studies on the venom from duckbill platypus Masaki Kita Sun, 01 Apr 2012 18:43:52 +0100 http://dx.doi.org/10.1351/PAC-CON-11-08-18 http://dx.doi.org/10.1351/PAC-CON-11-08-18 Tantalum carbide-graphite composite film synthesized by hot-filament chemical vapor deposition Mubarak Ali and Mustafa Ürgen Sat, 31 Mar 2012 23:42:01 +0100 http://dx.doi.org/10.1351/PAC-CON-11-12-01 http://dx.doi.org/10.1351/PAC-CON-11-12-01 Access to molecular complexity via gold- and platinum-catalyzed cascade reactions Sabyasachi Bhunia and Rai-Shung Liu Thu, 29 Mar 2012 21:45:41 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-13 http://dx.doi.org/10.1351/PAC-CON-11-09-13 An acyl-Claisen approach to the synthesis of lignans and substituted pyrroles David Barker, Benjamin Dickson, Nora Dittrich and Claire E. Rye Sun, 25 Mar 2012 22:38:23 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-27 http://dx.doi.org/10.1351/PAC-CON-11-09-27 Dynamic boronic acid-mediated autoligation of DNA strands Michael Smietana, Anthony R. Martin and Jean-Jacques Vasseur Sun, 25 Mar 2012 22:33:21 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-28 http://dx.doi.org/10.1351/PAC-CON-11-09-28 Recent Sino-Italian collaborative studies on marine organisms from the South China Sea Yue-Wei Guo, Margherita Gavagnin, Marianna Carbone, Ernesto Mollo and Guido Cimino Sun, 25 Mar 2012 22:14:01 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-04 http://dx.doi.org/10.1351/PAC-CON-11-09-04 Formation of C–C bonds via ruthenium-catalyzed transfer hydrogenation Joseph Moran and Michael J. Krische Tue, 13 Mar 2012 18:35:57 +0100 http://dx.doi.org/10.1351/PAC-CON-11-10-18 http://dx.doi.org/10.1351/PAC-CON-11-10-18 Designer chiral phase-transfer catalysts for green sustainable chemistry Keiji Maruoka Tue, 13 Mar 2012 18:27:25 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-31 http://dx.doi.org/10.1351/PAC-CON-11-09-31 Spiroketals: Toward the synthesis of 39‑oxobistramide K Malgorzata Commandeur, Claude Commandeur and Janine Cossy Tue, 28 Feb 2012 16:55:01 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-06 http://dx.doi.org/10.1351/PAC-CON-11-09-06 Studies toward the total synthesis of naturally occurring pyranonaphthoquinones from Ventilago harmandiana Sopanat Kongsriprapan, Chutima Kuhakarn, Pramchai Deelertpaiboon, Kanda Panthong, Patoomratana Tuchinda, Manat Pohmakotr and Vichai Reutrakul Tue, 14 Feb 2012 17:02:41 +0100 http://dx.doi.org/10.1351/PAC-CON-11-08-24 http://dx.doi.org/10.1351/PAC-CON-11-08-24 Conformationally constrained and nanoparticle‑targeted paclitaxels David G. I. Kingston, Lawrence Tamarkin and Giulio F. Paciotti Thu, 09 Feb 2012 17:29:13 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-02 http://dx.doi.org/10.1351/PAC-CON-11-09-02 Synthesis and structure–activity studies of simplified analogues of aplysiatoxin with antiproliferative activity like bryostatin-1 Kazuhiro Irie, Masayuki Kikumori, Hiroaki Kamachi, Keisuke Tanaka, Akira Murakami, Ryo C. Yanagita, Harukuni Tokuda, Nobutaka Suzuki, Hiroshi Nagai, Kiyotake Suenaga and Yu Nakagawa Wed, 08 Feb 2012 21:32:37 +0100 http://dx.doi.org/10.1351/PAC-CON-11-08-22 http://dx.doi.org/10.1351/PAC-CON-11-08-22 Assignment of stereochemistry in open-chain steroidal saponins Victoria L. Challinor and James J. De Voss Mon, 06 Feb 2012 17:29:38 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-12 http://dx.doi.org/10.1351/PAC-CON-11-09-12 Accessing chemical diversity by stereoselective gold-catalyzed manipulation of allylic and propargylic alcohols Gianpiero Cera, Michel Chiarucci and Marco Bandini Fri, 03 Feb 2012 00:19:20 +0100 http://dx.doi.org/10.1351/PAC-CON-11-09-05 http://dx.doi.org/10.1351/PAC-CON-11-09-05 Catalytic asymmetric synthesis using chirality‑switchable helical polymer as a chiral ligand Michinori Suginome, Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada and Yuto Akai Fri, 03 Feb 2012 00:08:38 +0100 http://dx.doi.org/10.1351/PAC-CON-11-08-23 http://dx.doi.org/10.1351/PAC-CON-11-08-23 Systematic isolation of microbial metabolites for natural products depository (NPDepo) Hiroyuki Osada and Toshihiko Nogawa Thu, 08 Dec 2011 19:28:39 +0100 http://dx.doi.org/10.1351/PAC-CON-11-08-11 http://dx.doi.org/10.1351/PAC-CON-11-08-11 Synthetic approaches to [5,6]‑benzannulated spiroketal natural products Michael C. McLeod, Margaret A. Brimble, Dominea C. K. Rathwell, Zoe E. Wilson and Tsz-Ying Yuen Sat, 29 Oct 2011 19:11:41 +0100 http://dx.doi.org/10.1351/PAC-CON-11-08-06 http://dx.doi.org/10.1351/PAC-CON-11-08-06 gem-Dibromocyclopropanes and enzymatically derived cis-1,2-dihydrocatechols as building blocks in alkaloid synthesis Martin G. Banwell, Nadia Yuqian Gao, Xinghua Ma, Laurent Petit, Lorenzo V. White, Brett D. Schwartz, Anthony C. Willis and Ian A. Cade Sun, 02 Oct 2011 13:59:01 +0100 http://dx.doi.org/10.1351/PAC-CON-11-07-05 http://dx.doi.org/10.1351/PAC-CON-11-07-05