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Project: Experimental Thermodynamics Vol. VIII.  Applied Thermodynamics of Fluids

Number: 2008-014-1-100
Start: 01 May 2008
Project of
Chair:
Members:
Objective

The intent of this volume is to update and reprint Experimental Thermodynamics Volume V, Equations of state for Fluids and Fluid Mixtures (ISBN-10: 0444503846) and first published in Oct 2000. This text is out of print and because it was in two volumes with 928 pages was not always accessible to the intended practitioners within academia, government and industry.

Description

The revised edition will expand the principal approaches for developing equations of state with a practical bias while retaining the theoretical basis. The emphasis of application and use will be expanded over the previous version as will the strength and weaknesses of each approach. The discussion on self - assembled systems has been removed and a chapter concerning chemically reacting systems added.

  1. Introduction
  2. Fundamental Considerations
    1. Basic Thermodynamics
    2. Mixing functions
    3. Fugacity
    4. Activity
    5. The phase rule
    6. Equilibrium
  3. Virial Equation of State
    1. Volumetric behavior
    2. Theory
    3. Virial coefficients
    4. Calculation of virial coefficients
  4. Cubic and Generalized van der Waals equations
    1. Equation forms
    2. Pure components
    3. Mixtures
    4. Predictions
    5. Industrial applications
  5. Mixing and Combining Rules
  6. Principles of Corresponding-States
    1. Theory
    2. Mixtures
    3. Industrial applications and extension to transport
  7. Mixtures of Dissimilar Molecules
  8. SAFT Associating Fluids and Fluid Mixtures
    1. Theory
    2. Applications by example to industrially specific systems
  9. Continuous Thermodynamics
    1. Continuous thermodynamics and application to phase stability
  10. Critical Region
    1. Theory
    2. Scaled equations
    3. Crossover
    4. Isomorphic description of phases
    5. Vapour liquid crossover
    6. Application to industrial issues of gas condensates
  11. Ionic Fluids
    1. Applicable methods
    2. Industrial application
    3. Classical
    4. IE methods
    5. Near critical fluids
  12. Multiparameter Equations of State
    1. Approaches
    2. Helmholtz function and the fundamental equations
    3. Fitting algorithms
    4. Application to pure fluids and mixtures including natural gas
  13. Chemical reacting systems
  14. Applied non-equilibrium thermodynamics

About 30 pages per chapter with a total of 450 pages

Progress

* project announcement published in Chem. Int. Sep 2008