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Pure Appl. Chem., 1988, Vol. 60, No. 1, pp. 13-20

http://dx.doi.org/10.1351/pac198860010013

Asymmetric synthesis via the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)

S. G. Davies

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  • Davies Stephen G., Fletcher Ai M., Maberly Timothy R., Thomson James E.: Stereochemical aspects of nucleophilic addition reactions to alkoxycarbene cations of the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)]. New J. Chem. 2013, 37, 3406. <http://dx.doi.org/10.1039/c3nj00518f>
  • Linden Anthony, Llovera Ligia, Herrera Julio, Dorta Reto, Agrifoglio Giuseppe, Dorta Romano: “Chiral-at-Metal” Hemilabile Nickel Complexes with a Latent d10-ML2 Configuration: Receiving Substrates with Open Arms. Organometallics 2012, 31, 6162. <http://dx.doi.org/10.1021/om300484z>
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  • Nongbri Saphidabha L., Das Babulal, Rao Kollipara Mohan: Isolation and spectral studies of water-soluble η 5-cyclichydrocarbon rhodium and iridium complexes with pyridyl diketone analogues bonded through κ 2-N∩O, κ 4–N∩O, and κ3 -N-C-N modes. J  Coord Chem 2012, 65, 875. <http://dx.doi.org/10.1080/00958972.2012.664638>
  • Gupta Gajendra, Therrien Bruno, Park Sunhong, Lee Shim Sung, Kim Jinkwon: Syntheses and structural studies of mononuclear arene ruthenium complexes with nitrogen-based chelating ligands. Journal of Coordination Chemistry 2012, 65, 2523. <http://dx.doi.org/10.1080/00958972.2012.697159>
  • Gupta Gajendra, Zheng Chong, Wang Peng, Rao Kollipara Mohan: Mononuclear Complexes of Platinum Group Metals Containing η6- and η5-Cyclic Π-Perimeter Hydrocarbon and Pyridylpyrazolyl Derivatives: Syntheses and Structural Studies. Z anorg allg Chem 2010, 636, 758. <http://dx.doi.org/10.1002/zaac.200900475>
  • Gupta Gajendra, Prasad Kota Thirumala, Rao Anna Venkateswara, Geib Steven J., Das Babulal, Rao Kollipara Mohan: Novel mononuclear η5-pentamethylcyclopentadienyl complexes of platinum group metals bearing pyrazolylpyridazine ligands: Syntheses and spectral studies. Inorg Chim Ada 2010, 363, 2287. <http://dx.doi.org/10.1016/j.ica.2010.03.052>
  • Gupta Gajendra, Prasad Kota Thirumala, Das Babulal, Rao Kollipara Mohan: Study of half-sandwich platinum group metal complexes bearing dpt-NH2 ligand. J Polyhedron 2010, 29, 904. <http://dx.doi.org/10.1016/j.poly.2009.10.016>
  • Gupta Gajendra, Yap Glenn P.A., Therrien Bruno, Mohan Rao Kollipara: Study of novel η5-cyclopentadienyl and η6-arene platinum group metal complexes containing a N4-type ligand and their structural characterization. J Polyhedron 2009, 28, 844. <http://dx.doi.org/10.1016/j.poly.2008.12.050>
  • Pollock Ciara L., Saunders Graham C., Smyth E.C.M. Sarah, Sorokin Vladimir I.: Fluoroarylphosphines as ligands. J FLUORINE CHEM 2008, 129, 142. <http://dx.doi.org/10.1016/j.jfluchem.2007.11.003>
  • Prasad Kota Thirumala, Therrien Bruno, Rao Kollipara Mohan: Cationic half-sandwich complexes (Rh,Ir,Ru) containing 2-substituted-1,8-naphthyridine chelating ligands: Syntheses, X-ray structure analyses and spectroscopic studies. J Organomet Chem 2008, 693, 3049. <http://dx.doi.org/10.1016/j.jorganchem.2008.06.026>
  • Case-Green Stephen C., Davies Stephen G., Roberts Paul M., Russell Angela J., Thomson James E.: Asymmetric synthesis of tetrahydrolipstatin and valilactone. Tet Asymm 2008, 19, 2620. <http://dx.doi.org/10.1016/j.tetasy.2008.11.012>
  • Carmona Daniel, Lamata M. Pilar, Viguri Fernando, Ferrer Joaquina, García Néstor, Lahoz Fernando J., Martín M. Luisa, Oro Luis A.: Chiral Half-Sandwich Ruthenium(II) Complexes as Catalysts in 1,3-Dipolar Cycloaddition Reactions of Nitrones with Methacrolein. Eur J Inorg Chem 2006, 2006, 3155. <http://dx.doi.org/10.1002/ejic.200600408>
  • Kollipara Mohan R., Govindaswamy Padavattan: Syntheses and characterization of η 5-pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes containing polypyridyls. J Coord Chem 2006, 59, 663. <http://dx.doi.org/10.1080/00958970500271032>
  • Schwarz Markus, Vollmann Marc, Wartchow Rudolf, Butenschön Holger: Synthesis and cyclic voltammetry of some new metal carbene substituted cyclopentadienyliron half sandwich complexes. J Organomet Chem 2005, 690, 2263. <http://dx.doi.org/10.1016/j.jorganchem.2005.02.030>
  • Singh Keisham Sarjit, Mozharivskyj Yurij A., Thöne Carsten, Kollipara Mohan Rao: New mononuclear ruthenium complexes of η5-cyclichydrocarbon containing azine ligands: Syntheses, spectral and structural studies. J Organomet Chem 2005, 690, 3720. <http://dx.doi.org/10.1016/j.jorganchem.2005.05.001>
  • Govindaswamy Padavattan, Mozharivskyj Yurij A., Kollipara Mohan Rao: Syntheses, spectral and structural studies of Schiff base complexes of η5-pentamethylcyclopentadienyl rhodium and iridium. J Polyhedron 2005, 24, 1710. <http://dx.doi.org/10.1016/j.poly.2005.04.034>
  • Davies Stephen G., Smith Andrew D., Price Paul. D.: The conjugate addition of enantiomerically pure lithium amides as homochiral ammonia equivalents: scope, limitations and synthetic applications. Tet Asymm 2005, 16, 2833. <http://dx.doi.org/10.1016/j.tetasy.2005.08.006>
  • Davies Stephen G., Dupont Jairton, Easton Robert J.C., Ichihara Osamu, McKenna Jeffrey M., Smith Andrew D., de Sousa José A.A.: Stereoselective conjugate addition reactions of lithium amides to α,β-unsaturated chiral iron acyl complexes [(η5-C5H5)Fe(CO)(PPh3)(COCHCHR)]. J Organomet Chem 2004, 689, 4184. <http://dx.doi.org/10.1016/j.jorganchem.2004.04.046>
  • Carmona Daniel, Lamata María Pilar, Oro Luis A.: Half-Sandwich Complexes with Aminocarboxylate Ligands and Their Use as Enantioselective Hydrogen Transfer Catalysts. Eur J Inorg Chem 2002, 2002, 2239. <http://dx.doi.org/10.1002/1099-0682(200209)2002:9<2239::AID-EJIC2239>3.0.CO;2-1>
  • Schenk Wolfdieter A: Stereoselective addition reactions of ruthenium thioaldehyde complexes. J Organomet Chem 2002, 661, 129. <http://dx.doi.org/10.1016/S0022-328X(02)01820-X>
  • Davies David L, Fawcett John, Garratt Shaun A, Russell David R: Cp*rhodium and iridium complexes with bisoxazolines: synthesis, fluxionality and applications as asymmetric catalysts for Diels–Alder reactions. J Organomet Chem 2002, 662, 43. <http://dx.doi.org/10.1016/S0022-328X(02)01859-4>
  • Brunner Henri: Stability of the Metal Configuration in Chiral-at-Metal Half-Sandwich Compounds. Eur J Inorg Chem 2001, 2001, 905. <http://dx.doi.org/10.1002/1099-0682(200104)2001:4<905::AID-EJIC905>3.0.CO;2-V>
  • Schenk Wolfdieter A., Bezler Jürgen, Burzlaff Nicolai, Hagel Michael, Steinmetz Bernhard: Chiral Ruthenium–Sulfene Complexes – Synthesis and C–C Coupling Reactions. Eur J Inorg Chem 2000, 2000, 287. <http://dx.doi.org/10.1002/(SICI)1099-0682(200002)2000:2<287::AID-EJIC287>3.0.CO;2-V>
  • Brunner Henri: Optisch aktive metallorganische Verbindungen der Übergangselemente mit chiralen Metallatomen. Angew Chem 1999, 111, 1248. <http://dx.doi.org/10.1002/(SICI)1521-3757(19990503)111:9<1248::AID-ANGE1248>3.0.CO;2-K>
  • Jablonski Chet, Zhou Zhongxin, Bridson John: Synthesis, structure and reactivity of bidentate 2-ketopyrrolyl cobalt(III) phosphonates and phosphinates. Inorg Chim Ada 1997, 254, 315. <http://dx.doi.org/10.1016/S0020-1693(96)05184-5>
  • Davies David L., Fawcett John, Krafczyk Roland, Russell David R.: Arene ruthenium complexes with chiral Schiff bases derived from pyridine-2-carboxaldehyde or 2-acetylpyridine. J Organomet Chem 1997, 545-546, 581. <http://dx.doi.org/10.1016/S0022-328X(97)00410-5>
  • Beckett R.Paul, Burgess Vicky A., Davies Stephen G., Krippner Guy Y., Sutton Kevin H., Whittaker Mark: Application of the chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] to the stereoselective formation of 4-substituted-1,4-dihydronicotinoyl complexes. Inorg Chim Ada 1996, 251, 265. <http://dx.doi.org/10.1016/S0020-1693(96)05279-6>
  • Wang Tein-Fu, Juang Jung-Pin, Wen Yuh-Sheng: Preparations of novel half-sandwich iron carbonyl phosphine complexes: Intramolecular link between the cyclopentadienyl and the phosphine ligand. J Organomet Chem 1995, 503, 117. <http://dx.doi.org/10.1016/0022-328X(95)05542-W>
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