CrossRef enabled

PAC Archives

Archive →

Pure Appl. Chem., 1996, Vol. 68, No. 4, pp. 785-788

http://dx.doi.org/10.1351/pac199668040785

Stable silylenes: synthesis, structure, reactions

R. West and Michael Denk

CrossRef Cited-by theme picture

CrossRef Cited-by Linking

  • Singh Amritpal, Goel Neetu: DFT study of mechanism of cycloaddition of carbondioxide with tertiary-aziridine. Struct Chem 2014. <http://dx.doi.org/10.1007/s11224-014-0399-1>
  • Junold Konstantin, Baus Johannes A., Burschka Christian, Vent-Schmidt Thomas, Riedel Sebastian, Tacke Reinhold: Five-Coordinate Silicon(II) Compounds with Si–M Bonds (M = Cr, Mo, W, Fe): Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II) as a Ligand in Transition-Metal Complexes. Inorg. Chem. 2013, 52, 11593. <http://dx.doi.org/10.1021/ic401954e>
  • Biswas Abul Kalam, Lo Rabindranath, Ganguly Bishwajit: First Principles Studies toward the Design of Silylene Superbases: A Density Functional Theory Study. J. Phys. Chem. A 2013, 117, 3109. <http://dx.doi.org/10.1021/jp401076j>
  • Rodriguez Ricardo, Troadec Thibault, Kato Tsuyoshi, Saffon-Merceron Nathalie, Sotiropoulos Jean-Marc, Baceiredo Antoine: Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene. Angew. Chem. 2012, 124, 7270. <http://dx.doi.org/10.1002/ange.201201581>
  • Junold Konstantin, Baus Johannes A., Burschka Christian, Tacke Reinhold: Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand. Angew. Chem. 2012, 124, 7126. <http://dx.doi.org/10.1002/ange.201203109>
  • Rodriguez Ricardo, Troadec Thibault, Kato Tsuyoshi, Saffon-Merceron Nathalie, Sotiropoulos Jean-Marc, Baceiredo Antoine: Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene. Angew. Chem. Int. Ed. 2012, 51, 7158. <http://dx.doi.org/10.1002/anie.201201581>
  • Junold Konstantin, Baus Johannes A., Burschka Christian, Tacke Reinhold: Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand. Angew. Chem. Int. Ed. 2012, 51, 7020. <http://dx.doi.org/10.1002/anie.201203109>
  • KIRA MITSUO: Reactions of a stable dialkylsilylene and their mechanisms. J Chem Sci 2012, 124, 1205. <http://dx.doi.org/10.1007/s12039-012-0318-1>
  • Kassaee M.Z., Zandi H., Haerizade B.N., Ghambarian M.: Effects of α-mono heteroatoms (N vs. P), and β-conjugation on cyclic silylenes. Computational and Theoretical Chemistry 2012, 1001, 39. <http://dx.doi.org/10.1016/j.comptc.2012.10.005>
  • Azhakar Ramachandran, Ghadwal Rajendra S., Roesky Herbert W., Wolf Hilke, Stalke Dietmar: Stabilization of Low Valent Silicon Fluorides in the Coordination Sphere of Transition Metals. S J Am Chem Soc 2012, 134, 2423. <http://dx.doi.org/10.1021/ja210697p>
  • West Robert: Inorganic chemistry: Two-armed silicon. j nature 2012, 485, 49. <http://dx.doi.org/10.1038/485049a>
  • Sen Sakya S., Khan Shabana, Samuel Prinson P., Roesky Herbert W.: Chemistry of functionalized silylenes. Chem Sci 2012, 3, 659. <http://dx.doi.org/10.1039/c1sc00757b>
  • Ghadwal Rajendra S., Roesky Herbert W., Pröpper Kevin, Dittrich Birger, Klein Susanne, Frenking Gernot: A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms. angew chemie 2011, 123, 5486. <http://dx.doi.org/10.1002/ange.201101320>
  • Asay Matthew, Inoue Shigeyoshi, Driess Matthias: Aromatic Ylide-Stabilized Carbocyclic Silylene. angew chemie 2011, 123, 9763. <http://dx.doi.org/10.1002/ange.201104805>
  • Ghadwal Rajendra S., Roesky Herbert W., Pröpper Kevin, Dittrich Birger, Klein Susanne, Frenking Gernot: A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms. Angew Chem Int E 2011, 50, 5374. <http://dx.doi.org/10.1002/anie.201101320>
  • Asay Matthew, Inoue Shigeyoshi, Driess Matthias: Aromatic Ylide-Stabilized Carbocyclic Silylene. Angew Chem Int E 2011, 50, 9589. <http://dx.doi.org/10.1002/anie.201104805>
  • Khan Shabana, Sen Sakya S., Kratzert Daniel, Tavčar Gašper, Roesky Herbert W., Stalke Dietmar: Synthesis of Stable Silicon Heterocycles by Reaction of Organic Substrates with a Chlorosilylene [PhC(NtBu)2SiCl]. Chemistry A European Journal 2011, 17, 4283. <http://dx.doi.org/10.1002/chem.201001901>
  • Zhang Shu-Hua, Yeong Hui-Xian, So Cheuk-Wai: Reactivity of a Silylsilylene Bearing a Functionalized Diaminochlorosilyl Substituent. Chem Eur J 2011, 17, 3490. <http://dx.doi.org/10.1002/chem.201002611>
  • Azhakar Ramachandran, Tavčar Gašper, Roesky Herbert W., Hey Jakob, Stalke Dietmar: Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct. Eur J Inorg Chem 2011, 2011, 475. <http://dx.doi.org/10.1002/ejic.201001188>
  • Jana Anukul, Azhakar Ramachandran, Sarish Sankaranarayana Pillai, Samuel Prinson P., Roesky Herbert W., Schulzke Carola, Koley Debasis: Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline. Euro J Inorg Chem 2011, 2011, 5006. <http://dx.doi.org/10.1002/ejic.201100661>
  • Sun Long, Jin Guolian, Feng Wenling, Lu Pengfei, He Maoxia, Xie Ju: Cycloaddition reactions of N-heterocyclic stable silylenes with ethylene and formaldehyde. J Organomet Chem 2011, 696, 841. <http://dx.doi.org/10.1016/j.jorganchem.2010.10.014>
  • Vessally E., Nikoorazm M., Esmaili F., Fereyduni E.: Substitution effects at α-position of divalent five-membered ring XC4H3M (M=C, Si and Ge). J Organomet Chem 2011, 696, 932. <http://dx.doi.org/10.1016/j.jorganchem.2010.10.026>
  • Ghadwal Rajendra S., Azhakar Ramachandran, Pröpper Kevin, Holstein Julian J., Dittrich Birger, Roesky Herbert W.: N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0). Inorg. Chem. 2011, 50, 8502. <http://dx.doi.org/10.1021/ic201096c>
  • Sen Sakya S., Hey Jakob, Herbst-Irmer Regine, Roesky Herbert W., Stalke Dietmar: Striking Stability of a Substituted Silicon(II) Bis(trimethylsilyl)amide and the Facile Si–Me Bond Cleavage without a Transition Metal Catalyst. J Am Chcm Soc 2011, 133, 12311. <http://dx.doi.org/10.1021/ja205369h>
  • Ghadwal Rajendra S., Azhakar Ramachandran, Roesky Herbert W., Pröpper Kevin, Dittrich Birger, Klein Susanne, Frenking Gernot: Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride. S J Am Chem Soc 2011, 133, 17552. <http://dx.doi.org/10.1021/ja206702e>
  • Yao Shenglai, Xiong Yun, Driess Matthias: Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules. Organomet 2011, 30, 1748. <http://dx.doi.org/10.1021/om200017h>
  • Szilvási Tibor, Nyíri Kinga, Veszprémi Tamás: Unique Insertion Mechanisms of Bis-dehydro-β-diketiminato Silylene. Organomettalics 2011, 30, 5344. <http://dx.doi.org/10.1021/om200424k>
  • Szilvási Tibor, Veszprémi Tamás: On the mechanism of the reaction of white phosphorus with silylenes. Dalton Trans 2011, 40, 7193. <http://dx.doi.org/10.1039/c0dt01685c>
  • Chen Jian-Yi, Su Ming-Der: Theoretical investigations of the reactivities of saturated five-membered ring N-heterocyclic carbenes with heavier Group 14 elements. Dalton Trans 2011, 40, 7898. <http://dx.doi.org/10.1039/c1dt10054h>
  • Xiong Yun, Yao Shenglai, Driess Matthias: Synthesis and Rearrangement of Stable NHC→Silylene Adducts and Their Unique Reactivity towards Cyclohexylisocyanide. Chem Asian J 2010, 5, 322. <http://dx.doi.org/10.1002/asia.200900434>
  • Ghadwal Rajendra S., Roesky Herbert W., Merkel Sebastian, Stalke Dietmar: Ambiphilicity of Dichlorosilylene in a Single Molecule. Chem Eur J 2010, 16, 85. <http://dx.doi.org/10.1002/chem.200902930>
  • WEST R., DENK M.: ChemInform Abstract: Stable Silylenes: Synthesis, Structure, Reactions. ChemInform 2010, 27, no. <http://dx.doi.org/10.1002/chin.199649293>
  • Abraham Sascha, Schmatz Stefan, Klingebiel Uwe, Fischer Andreas: Intramolekulare Ringerweiterung eines 2-Lithium-anilido-2-fluoro-1,3-diaza-2-silacyclopentens zum 1,3,5-Triaza-7-bora-2-silacyclohepten - Experimentelle und Quantenchemische Ergebnisse. Z anorg allg Chem 2010, 636, 576. <http://dx.doi.org/10.1002/zaac.200900341>
  • Zark P., Schäfer A., Mitra A., Haase D., Saak W., West R., Müller T.: Synthesis and reactivity of N-aryl substituted N-heterocyclic silylenes. J Organomet Chem 2010, 695, 398. <http://dx.doi.org/10.1016/j.jorganchem.2009.10.034>
  • Rynin S.S., Faustov V.I., Boganov S.E., Egorov M.P., Nefedov O.M.: Computational study of reaction pathways in the course of interaction of deactivated silylenes with buta-1,3-diene. J Organomet Chem 2010, 695, 2345. <http://dx.doi.org/10.1016/j.jorganchem.2010.06.023>
  • Ullah Farman, Kühl Olaf, Rehman Wajid, Jones Peter G., Heinicke Joachim: Novel highly electron-deficient quinoxaline-annulated 1,3,2-diazagermol- and diazastannol-2-ylidenes, stabilized as LiCl adducts. J Polyhedron 2010, 29, 1041. <http://dx.doi.org/10.1016/j.poly.2009.12.014>
  • Ghadwal Rajendra S., Roesky Herbert W., Granitzka Markus, Stalke Dietmar: A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene. J Am Chem Soc 2010, 132, 10018. <http://dx.doi.org/10.1021/ja104386g>
  • Sen Sakya S., Roesky Herbert W., Stern Daniel, Henn Julian, Stalke Dietmar: High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene. J Am Chem Soc 2010, 132, 1123. <http://dx.doi.org/10.1021/ja9091374>
  • Kira Mitsuo: An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds. Chem Commun 2010, 46, 2893. <http://dx.doi.org/10.1039/c002806a>
  • Mandal Swadhin K., Roesky Herbert W.: Interstellar molecules: guides for new chemistry. Chem Commun 2010, 46, 6016. <http://dx.doi.org/10.1039/c0cc01003k>
  • Nyíri Kinga, Szilvási Tibor, Veszprémi Tamás: The mechanism and energetics of insertion reactions of silylenes. Dalton Trans 2010, 39, 9347. <http://dx.doi.org/10.1039/c0dt00197j>
  • Schäfer Annemarie, Schäfer André, Müller Thomas: Silaimidazolium and silaimidazolidinium ions. Dalton Trans 2010, 39, 9296. <http://dx.doi.org/10.1039/c0dt00313a>
  • Iwamoto Takeaki, Ohnishi Nobuyoshi, Gui Zhenyu, Ishida Shintaro, Isobe Hiroyuki, Maeda Satoshi, Ohno Koichi, Kira Mitsuo: Synthesis and structure of stable base-free dialkylsilanimines. New J Chem 2010, 34, 1637. <http://dx.doi.org/10.1039/c0nj00121j>
  • Sheberla Dennis, Tumanskii Boris, Tomasik Adam C., Mitra Amitabha, Hill Nicholas J., West Robert, Apeloig Yitzhak: Different electronic structure of phosphonyl radical adducts of N-heterocyclic carbenes, silylenes and germylenes: EPR spectroscopic study and DFT calculations. Chem Sci 2010, 1, 234. <http://dx.doi.org/10.1039/c0sc00143k>
  • Xiong Yun, Yao Shenglai, Driess Matthias: Striking Reactivity of a Stable, Zwitterionic Silylene Towards Substituted Diazomethanes, Azides, and Isocyanides. Chem Eur J 2009, 15, 8542. <http://dx.doi.org/10.1002/chem.200901337>
  • Chrostowska Anna, Lemierre Virginie, Dargelos Alain, Baylère Patrick, Leigh William J., Rima Ghassoub, Weber Lothar, Schimmel Michaela: Gas-phase synthesis and characterization of heteroleptic divalent germanium compounds by FVT/UV-PES. J Organomet Chem 2009, 694, 43. <http://dx.doi.org/10.1016/j.jorganchem.2008.09.069>
  • Wang Yong, Ma Jing: Silylenes and germylenes: The activation of H–H bond in hydrogen molecule. J Organomet Chem 2009, 694, 2567. <http://dx.doi.org/10.1016/j.jorganchem.2009.03.051>
  • Chernov Oleg V., Smirnov Aleksandr Yu., Portnyagin Ivan A., Khrustalev Victor N., Nechaev Mikhail S.: Heteroleptic tin (II) dialkoxides stabilized by intramolecular coordination Sn(OCH2CH2NMe2)(OR) (R=Me, Et, iPr, tBu, Ph). Synthesis, structure and catalytic activity in polyurethane synthesis. J Organomet Chem 2009, 694, 3184. <http://dx.doi.org/10.1016/j.jorganchem.2009.05.014>
  • Portnyagin Ivan A., Nechaev Mikhail S.: Germylene and stannylene (Me2NCH2CH2O)2E as strong σ-donor ligands for transition metal complexes [ML(CO)n] (E=Ge, Sn; M=Cr, Mo, W, n=4 or 5; M=Fe, n=4). Synthesis, spectroscopic and theoretical study. J Organomet Chem 2009, 694, 3149. <http://dx.doi.org/10.1016/j.jorganchem.2009.05.017>
  • Schoeller Wolfgang W.: Autocatalytic degradation of white phosphorus with silylenes. Phys Chem Chem Phys 2009, 11, 5273. <http://dx.doi.org/10.1039/b818396a>
  • Kong Lingbing, Zhang Jianying, Song Haibin, Cui Chunming: N-Aryl substituted heterocyclic silylenes. Dalton Trans 2009, 5444. <http://dx.doi.org/10.1039/b905905a>
  • Vessally E.: Singlet–triplet splitting and stability of divalent five-membered ring C4H4M, C4H6M, and C4H8M (M = C, Si, Ge, Sn, and Pb). Heteroatom Chem 2008, 19, 245. <http://dx.doi.org/10.1002/hc.20428>
  • Zhang Ming, Liu Xiaoli, Shi Chaojun, Ren Chunxia, Ding Yuqiang, Roesky Herbert W.: The Synthesis of (η3-C3H5)Pd{Si[N(tBu)CH]2}Cl and the Catalytic Property for Heck Reaction. Z anorg allg Chem 2008, 634, 1755. <http://dx.doi.org/10.1002/zaac.200800131>
  • Kassaee M.Z., Soleimani-Amiri S., Ghambarian M., Boazar F., Motamedi E., Morell Christophe, Hocquet Alexandre, Grand Andr��, Jamart-Gr��goire Brigitte: Divalency switch from carbenes to germylenes at theoretical levels. Journal of Molecular Structure: THEOCHEM 2008, 849, 37. <http://dx.doi.org/10.1016/j.theochem.2007.10.003>
  • Al-Ktaifani Mahmoud M., Hitchcock Peter B., Lappert Michael F., Nixon John F., Uiterweerd Philip: Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P–P bond of the hexaphospha-pentaprismane cage, P6C4tBu4: Crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2 -2,6). Dalton Trans 2008, 2825. <http://dx.doi.org/10.1039/b800458g>
  • Charmant Jonathan P. H., Haddow Mairi F., Hahn F. Ekkehardt, Heitmann Dennis, Fröhlich Roland, Mansell Stephen M., Russell Christopher A., Wass Duncan F.: Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes. Dalton Trans 2008, 6055. <http://dx.doi.org/10.1039/b808717b>
  • Ullah Farman, Bajor Gabor, Veszprémi Tamas, Jones Peter G., Heinicke Joachim W.: Stabilisierung unsymmetrisch anellierter Imidazol-2-ylidene gegenüber ihren höheren Gruppe-14-Homologen durch n-/π-HOMO-Inversion. Angew Chem 2007, 119, 2751. <http://dx.doi.org/10.1002/ange.200604516>
  • Ullah Farman, Bajor Gabor, Veszprémi Tamas, Jones Peter G., Heinicke Joachim W.: Stabilization of Unsymmetrically Annelated Imidazol-2-ylidenes with Respect to Their Higher Group 14 Homologues by n-/π-HOMO Inversion. Angew Chem Int Ed 2007, 46, 2697. <http://dx.doi.org/10.1002/anie.200604516>
  • Chen Chi-Hui, Su Ming-Der: The Mechanism of CX (X=F, Cl, Br, and I) Bond Activation in CX4 by a Stabilized Dialkylsilylene. Chem Eur J 2007, 13, 6932. <http://dx.doi.org/10.1002/chem.200601736>
  • Sievert N., Fischer A., Klingebiel U., Pal A., Noltemeyer M.: 2,2-Difluor-1,3-diaza-2-sila-cyclopenten – Synthese und Reaktionen. Z anorg allg Chem 2007, 633, 1223. <http://dx.doi.org/10.1002/zaac.200700107>
  • Kira Mitsuo, Iwamoto Takeaki, Ishida Shintaro: A Helmeted Dialkylsilylene. Bull Chem Soc Jpn 2007, 80, 258. <http://dx.doi.org/10.1246/bcsj.80.258>
  • Gehrhus Barbara, Hitchcock Peter B., Pongtavornpinyo Ruti, Zhang Lihong: Insights into the making of a stable silylene. Dalton Trans 2006, 1847. <http://dx.doi.org/10.1039/b514666f>
  • Kassaee M.Z., Arshadi S., Acedy M., Vessally E.: Singlet–triplet energy separations in divalent five-membered cyclic conjugated C5H3X, C4H3SiX, C4H3GeX, C4H3SnX, and C4H3PbX (X=H, F, Cl, and Br). J Organomet Chem 2005, 690, 3427. <http://dx.doi.org/10.1016/j.jorganchem.2005.04.030>
  • Kassaee M.Z., Musavi S.M., Ghambarian M.: Divalent propargylenic C2H2M group 14 elements:Structures and singlet���triplet energy splittings (M=C, Si, Ge, Sn and Pb). Journal of Molecular Structure: THEOCHEM 2005, 731, 225. <http://dx.doi.org/10.1016/j.theochem.2005.06.033>
  • Lemierre Virginie, Chrostowska Anna, Dargelos Alain, Baylère Patrick, Leigh William J., Harrington Cameron R.: Flash vacuum thermolysis of 3,4-dimethyl-1-germacyclopent-3-enes: UV photoelectron spectroscopic characterization of GeH2 and GeMe2. Appl Organometal Chem 2004, 18, 676. <http://dx.doi.org/10.1002/aoc.628>
  • Fredelake Bernd, Ebker Christina, Klingebiel Uwe, Noltemeyer Mathias, Schmatz Stefan: (Fluorosilyl)ethylenediamines and fluorosilyl-1,3-diaza-2-silacyclopentanes. J FLUORINE CHEM 2004, 125, 1007. <http://dx.doi.org/10.1016/j.jfluchem.2004.02.013>
  • Kira Mitsuo: Isolable silylene, disilenes, trisilaallene, and related compounds. J Organomet Chem 2004, 689, 4475. <http://dx.doi.org/10.1016/j.jorganchem.2004.05.054>
  • Hill Nicholas J., West Robert: Recent developments in the chemistry of stable silylenes. J Organomet Chem 2004, 689, 4165. <http://dx.doi.org/10.1016/j.jorganchem.2004.09.012>
  • Tokitoh Norihiro: Synthesis of Aromatic Species Containing a Heavier Group 14 Element by Taking Advantage of Kinetic Stabilization. Bull Chem Soc Jpn 2004, 77, 429. <http://dx.doi.org/10.1246/bcsj.77.429>
  • Müller Thomas: The chemical shift tensor of silylenes. J Organomet Chem 2003, 686, 251. <http://dx.doi.org/10.1016/S0022-328X(03)00542-4>
  • Maciejewski Hieronim, Avent Anthony G., Gehrhus Barbara, Hitchcock Peter B., Lappert Michael F.: Synthesis and characterisation of bis(amino)silylene–nickel(0), –palladium(II), –platinum(0), –platinum(II) and copper(I) complexes. J Organomet Chem 2003, 686, 321. <http://dx.doi.org/10.1016/S0022-328X(03)00560-6>
  • Weidenbruch Manfred: Some recent advances in the chemistry of silicon and its homologues in low coordination states. J Organomet Chem 2002, 646, 39. <http://dx.doi.org/10.1016/S0022-328X(01)01262-1>
  • Moigno Damien, Pavel Ioana, Kiefer Wolfgang, Jehle Heinrich, Malisch Wolfgang: A theoretical study of the reaction products created by irradiation of the carbonyl iron silyl complexes Cp(CO)2FeSiH2Me and Cp(CO)2FeCH2SiH3. J Organomet Chem 2002, 648, 155. <http://dx.doi.org/10.1016/S0022-328X(01)01469-3>
  • Herrmann Wolfgang A., Härter Peter, Gstöttmayr Christian W.K., Bielert Frank, Seeboth Nicolas, Sirsch Peter: Complexation of N-heterocyclic silylenes to Pd(0): formation of highly labile homoleptic complexes Pd[tBu)]4 and Pd[tBu)]3. J Organomet Chem 2002, 649, 141. <http://dx.doi.org/10.1016/S0022-328X(02)01110-5>
  • Gehrhus Barbara, Lappert Michael F.: Chemistry of thermally stable bis(amino)silylenes. J Organomet Chem 2001, 617-618, 209. <http://dx.doi.org/10.1016/S0022-328X(00)00729-4>
  • Schmedake Thomas A., Haaf Michael, Paradise Bryan J., Millevolte Anthony J., Powell Douglas R., West Robert: Electronic and steric properties of stable silylene ligands in metal(0) carbonyl complexes. J Organomet Chem 2001, 636, 17. <http://dx.doi.org/10.1016/S0022-328X(01)00765-3>
  • West Robert, Schmedake Thomas A., Haaf Michael, Becker James, Mueller Thomas: A Disilanyl Dianion and a Silyl Dianion from a Stable Silylene. Chem Lett 2001, 68. <http://dx.doi.org/10.1246/cl.2001.68>
  • Weidenbruch, Manfred: LOW COORDINATED COMPOUNDS OF GERMANIUM, TIN, AND LEAD: SOME RECENT RESULTS. MGMC 2001, 24, 621. <http://dx.doi.org/10.1515/MGMC.2001.24.9.621>
  • Haaf Michael, Schmedake Thomas A, Paradise Bryan J, West Robert: Synthesis and reactivity of the stable silylene N,N'-di-tert-butyl-1,3-diaza-2-sila-2-ylidene. Can J Chem 2000, 78, 1526. <http://dx.doi.org/10.1139/v00-014>
  • Cai Xiaoping, Gehrhus Barbara, Hitchcock Peter B, Lappert Michael F: Reactions of the stable bis(amino)silylene Si[{N(CH2tBu)}2C6H4-1,2] with group 3 or lanthanide metal organic compounds. Crystal structures of [Ln(η5-C5H5)3Si{[N(CH2tBu)]2C6H4-1,2}]·C7H8 (Ln = Y or Yb). Can J Chem 2000, 78, 1484. <http://dx.doi.org/10.1139/v00-044>
  • Weidenbruch Manfred: Some Silicon, Germanium, Tin, and Lead Analogues of Carbenes, Alkenes, and Dienes. Eur J Inorg Chem 1999, 1999, 373. <http://dx.doi.org/10.1002/(SICI)1099-0682(199903)1999:3<373::AID-EJIC373>3.0.CO;2-D>
  • Belzner Johannes, Dehnert Uwe, Ihmels Heiko, Müller Peter: New Dichlorosilanes, Cyclotrisilanes, and Silacyclopropanes as Precursors of Intramolecularly Coordinated Silylenes. Chem Eur J 1998, 4, 852. <http://dx.doi.org/10.1002/(SICI)1521-3765(19980515)4:5<852::AID-CHEM852>3.0.CO;2-7>
  • Heinicke Joachim, Meinel Susanne: Synthesis of silicon heterocycles via gas phase cycloaddition of aminomethylsilylenes. J Organomet Chem 1998, 561, 121. <http://dx.doi.org/10.1016/S0022-328X(98)00533-6>
  • Schäfer Annemarie, Saak Wolfgang, Weidenbruch Manfred, Marsmann Heinrich, Henkel Gerald: Compounds of Germanium and Tin, 22 – Reactions of a Silyene with a Germylene and a Stannylene: Formation of a Digermene with an Unusual Arrangement of the Substituents and of a Stannane. Chem Ber 1997, 130, 1733. <http://dx.doi.org/10.1002/cber.19971301205>